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XPS, UPS, TPD and TPR Studies of Oxygen Species Active in Silver-Catalysed Ethylene Epoxidation Full article

Journal Catalysis Letters
ISSN: 1011-372X , E-ISSN: 1572-879X
Output data Year: 1999, Volume: 57, Number: 4, Pages: 233-239 Pages count : 7 DOI: 10.1023/A:1019016120040
Tags Epoxidation, Ethylene, Isotope, Oxygen, Photoelectron spectroscopy, Silver, Temperature-programmed desorption
Authors Bukhtiyarov V.I. 1 , Kaichev V.V. 1 , Podgornov E.A. 1 , Prosvirin I.P. 1
Affiliations
1 Boreskov Institute of Catalysis, Lavrentieva prospekt 5, Novosibirsk 630090, Russia

Funding (1)

1 Russian Foundation for Basic Research 96-03-33891

Abstract: The covalent oxygen chemisorbed on silver has been characterised by XPS, UPS, TPD and TPR. It has been shown that this oxygen species active in ethylene epoxidation is characterised by full isotope scrambling in TPD spectra of O2 and the absence of UPS lines located below the silver 4d zone. Both the results testify its atomic origin.
Cite: Bukhtiyarov V.I. , Kaichev V.V. , Podgornov E.A. , Prosvirin I.P.
XPS, UPS, TPD and TPR Studies of Oxygen Species Active in Silver-Catalysed Ethylene Epoxidation
Catalysis Letters. 1999. V.57. N4. P.233-239. DOI: 10.1023/A:1019016120040 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Aug 24, 1998
Accepted: Jan 12, 1999
Published print: Mar 1, 1999
Identifiers:
Web of science: WOS:000079584500013
Scopus: 2-s2.0-0001239372
Elibrary: 13309620
Chemical Abstracts: 1999:218264
Chemical Abstracts (print): 130:324858
OpenAlex: W16013205
Citing:
DB Citing
Web of science 33
Scopus 34
Elibrary 35
OpenAlex 33
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