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XPS, UPS, TPD and TPR Studies of Oxygen Species Active in Silver-Catalysed Ethylene Epoxidation Full article

Journal Catalysis Letters
ISSN: 1011-372X , E-ISSN: 1572-879X
Output data Year: 1999, Volume: 57, Number: 4, Pages: 233-239 Pages count : 7 DOI: 10.1023/A:1019016120040
Tags Epoxidation, Ethylene, Isotope, Oxygen, Photoelectron spectroscopy, Silver, Temperature-programmed desorption
Authors Bukhtiyarov V.I. 1 , Kaichev V.V. 1 , Podgornov E.A. 1 , Prosvirin I.P. 1
Affiliations
1 Boreskov Institute of Catalysis, Lavrentieva prospekt 5, Novosibirsk 630090, Russia

Funding (1)

1 Russian Foundation for Basic Research 96-03-33891

Abstract: The covalent oxygen chemisorbed on silver has been characterised by XPS, UPS, TPD and TPR. It has been shown that this oxygen species active in ethylene epoxidation is characterised by full isotope scrambling in TPD spectra of O2 and the absence of UPS lines located below the silver 4d zone. Both the results testify its atomic origin.
Cite: Bukhtiyarov V.I. , Kaichev V.V. , Podgornov E.A. , Prosvirin I.P.
XPS, UPS, TPD and TPR Studies of Oxygen Species Active in Silver-Catalysed Ethylene Epoxidation
Catalysis Letters. 1999. V.57. N4. P.233-239. DOI: 10.1023/A:1019016120040 WOS Scopus РИНЦ OpenAlex ANCAN
Dates:
Submitted: Aug 24, 1998
Accepted: Jan 12, 1999
Published print: Mar 1, 1999
Identifiers:
≡ Web of science: WOS:000079584500013
≡ Scopus: 2-s2.0-0001239372
≡ Elibrary: 13309620
≡ OpenAlex: W16013205
≡ Chemical Abstracts: 1999:218264
≡ Chemical Abstracts (print): 130:324858
Citing:
≡ Web of science 33 Сбор данных от 13.02.2026
≡ Scopus 34 Сбор данных от 15.02.2026
≡ Elibrary 36 Сбор данных от 15.02.2026
≡ OpenAlex 33 Сбор данных от 15.02.2026
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