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Formation of Tetramethylethylene Radical Cations after Pentane Adsorption on Sulfated Zirconia Full article

Journal Catalysis Letters
ISSN: 1011-372X , E-ISSN: 1572-879X
Output data Year: 2000, Volume: 68, Number: 3-4, Pages: 209-214 Pages count : 6 DOI: 10.1023/A:1019039605154
Tags ESR, Pentane, Radical cations, Sulfated zirconia, Tetramethylethylene
Authors Bedilo Alexander F. 1 , Timoshok Alina V. 1 , Volodin Alexander M. 1
Affiliations
1 Boreskov Institute of Catalysis

Abstract: Tetramethylethylene radical cations have been registered by ESR after pentane adsorption on sulfated zirconia. The radical cations proved to be not stable in the presence of oxygen, only molecular oxygen radical anions being registered. Tetramethylethylene formation and pentane disproportionation are shown to occur under illumination within the same spectral region proving that the former is formed as a by-product of pentane transformations.
Cite: Bedilo A.F. , Timoshok A.V. , Volodin A.M.
Formation of Tetramethylethylene Radical Cations after Pentane Adsorption on Sulfated Zirconia
Catalysis Letters. 2000. V.68. N3-4. P.209-214. DOI: 10.1023/A:1019039605154 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Dec 13, 1999
Accepted: May 26, 2000
Published print: Sep 1, 2000
Identifiers:
Web of science: WOS:000089197400014
Scopus: 2-s2.0-0034276536
Elibrary: 13349031
Chemical Abstracts: 2001:120347
Chemical Abstracts (print): 134:195462
OpenAlex: W2260559880
Citing:
DB Citing
Web of science 7
Scopus 10
Elibrary 9
OpenAlex 9
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