Interaction of Hydrogen and n-Pentane with Sulfated Zirconia Full article
| Journal |
Catalysis Letters
ISSN: 1011-372X , E-ISSN: 1572-879X |
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| Output data | Year: 2000, Volume: 69, Number: 3-4, Pages: 189-193 Pages count : 5 DOI: 10.1023/A:1019017922418 | ||
| Tags | Alkanes, FTIR, Pentane, Skeletal isomerization, Sulfated zirconia | ||
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Abstract:
Interaction of hydrogen with sulfated zirconia catalysts was studied in situ at 473 K. Interaction of hydrogen with the sample evacuated at 673 K leads to the formation of new hydroxyl groups (wide bands near 3330 cm−1) and water (1620 cm−1). In the case of the sample evacuated at 873 K, SOH groups (3660 cm−1) and zirconium hydrides (1555 cm−1) form. Adsorption of n‐pentane on sulfated zirconia catalysts in the range of 253–383 K was studied. It was shown that hydrides and protonated cyclopentadienes form at low temperatures. At higher temperatures, aromatic compounds are formed mainly. The reaction mechanism is discussed.
Cite:
Paukshtis E.A.
, Kotsarenko N.S.
, Shmachkova V.P.
Interaction of Hydrogen and n-Pentane with Sulfated Zirconia
Catalysis Letters. 2000. V.69. N3-4. P.189-193. DOI: 10.1023/A:1019017922418 WOS Scopus РИНЦ ANCAN OpenAlex
Interaction of Hydrogen and n-Pentane with Sulfated Zirconia
Catalysis Letters. 2000. V.69. N3-4. P.189-193. DOI: 10.1023/A:1019017922418 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Feb 18, 2000 |
| Accepted: | Jul 18, 2000 |
| Published print: | Nov 1, 2000 |
Identifiers:
| Web of science: | WOS:000089945300012 |
| Scopus: | 2-s2.0-0040436307 |
| Elibrary: | 13337471 |
| Chemical Abstracts: | 2000:878666 |
| Chemical Abstracts (print): | 134:147241 |
| OpenAlex: | W120679479 |