Pd Oxidation under UHV in a Model Pd/Ceria-Zirconia Catalyst Full article
Journal |
Catalysis Letters
ISSN: 1011-372X , E-ISSN: 1572-879X |
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Output data | Year: 2001, Volume: 72, Number: 1-2, Pages: 39-44 Pages count : 6 DOI: 10.1023/A:1009092005849 | ||
Tags | Automotive exhaust catalyst, Ceria-zirconia, Oxygen storage, Palladium | ||
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Abstract:
A model planar catalyst was prepared by depositing Pd onto a thick (few μm) film of ceria–zirconia in ultrahigh vacuum (UHV), and the oxidation state of Pd and its support was determined by X-ray photoelectron spectroscopy, following thermal treatments in UHV, oxygen, or carbon monoxide. It was found that Pd could be oxidized simply by heating the catalyst in UHV, indicating that transfer of oxygen from the support to the metal is both thermodynamically favorable and facile.
Cite:
Smirnov M.Y.
, Graham G.W.
Pd Oxidation under UHV in a Model Pd/Ceria-Zirconia Catalyst
Catalysis Letters. 2001. V.72. N1-2. P.39-44. DOI: 10.1023/A:1009092005849 WOS Scopus РИНЦ ANCAN OpenAlex
Pd Oxidation under UHV in a Model Pd/Ceria-Zirconia Catalyst
Catalysis Letters. 2001. V.72. N1-2. P.39-44. DOI: 10.1023/A:1009092005849 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: | Oct 19, 2000 |
Accepted: | Dec 15, 2000 |
Published print: | Mar 1, 2001 |
Identifiers:
Web of science: | WOS:000168848200007 |
Scopus: | 2-s2.0-0035296948 |
Elibrary: | 13375731 |
Chemical Abstracts: | 2001:379352 |
Chemical Abstracts (print): | 135:81182 |
OpenAlex: | W1579082490 |