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Hydroxylation of Benzene with Oxygen and Hydrogen over Catalysts Containing Group VIII Metals and Heteropoly Compounds Full article

Journal Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308
Output data Year: 2005, Volume: 99, Number: 1-2, Pages: 193-198 Pages count : 6 DOI: 10.1016/j.cattod.2004.09.040
Tags Benzene, Hydrogen, Oxidation, Oxygen, Palladium, Platinum
Authors Kuznetsova N.I. 1 , Kuznetsova L.I. 1 , Likholobov V.A. 2 , Pez G.P. 3
Affiliations
1 Boreskov Institute of Catalysis, Prosp. Lavrentieva, 5, Novosibirsk 630090, Russia
2 Institute of Hydrocarbon Processing, Neftezavodskaya St., 54, Omsk 644040, Russia
3 Air Products and Chemicals, Inc., Corporate Science and Technology Center, 7201 Hamilton Blvd., Allentown, PA 18195-1501, USA

Funding (2)

1 Russian Foundation for Basic Research 03-03-32787
2 Council for Grants of the President of the Russian Federation НШ-2287.2003.3

Abstract: The vapor phase hydroxylation of benzene to phenol with a mixture of oxygen and hydrogen over silica supported bi-component catalysts containing Group VIII metals (M) and heteropoly compounds (HPC) was investigated. The productivity of the catalysts was ascertained for various metal and HPC combinations and a range of reaction conditions. The Pt–PMo12/SiO2 and Pd–PMo12/SiO2 catalysts of optimal composition provide up to 380 mol phenol/g-atom Pt or Pd/h. The observed catalysis appears to be associated with an interface between metal particles and those of the heteropoly compound, as illustrated by an HREM image of a Pt–PMo12/SiO2 sample.
Cite: Kuznetsova N.I. , Kuznetsova L.I. , Likholobov V.A. , Pez G.P.
Hydroxylation of Benzene with Oxygen and Hydrogen over Catalysts Containing Group VIII Metals and Heteropoly Compounds
Catalysis Today. 2005. V.99. N1-2. P.193-198. DOI: 10.1016/j.cattod.2004.09.040 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Published online: Dec 15, 2004
Published print: Jan 15, 2005
Identifiers:
Web of science: WOS:000228114200024
Scopus: 2-s2.0-14644415980
Elibrary: 13488577
Chemical Abstracts: 2005:224831
Chemical Abstracts (print): 142:448563
OpenAlex: W2073651226
Citing:
DB Citing
Web of science 46
Scopus 50
Elibrary 50
OpenAlex 48
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