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Development of Active Catalysts for Low Pt Loading Cathodes of PEMFC by Surface Tailoring of Nanocarbon Materials Full article

Conference 1st International Symposium on Carbon for Catalysis
18-20 Jul 2004 , Lausanne
Journal Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308
Output data Year: 2005, Volume: 102-103, Pages: 58-66 Pages count : 9 DOI: 10.1016/j.cattod.2005.02.007
Tags Carbon nanofiber, Catalyst, Cathode, CNF, Low loading, Nanocarbon, PEMFC, Platinum, Supermicroporous carbon
Authors Ismagilov Z.R. 1 , Kerzhentsev M.A. 1 , Shikina N.V. 1 , Lisitsyn A.S. 1 , Okhlopkova L.B. 1 , Barnakov Ch.N. 2 , Sakashita Masao 3 , Iijima Takashi 4 , Tadokoro Kenichiro 4
Affiliations
1 Boreskov Institute of Catalysis, Prospekt Akademika Lavrentieva 5, Novosibirsk 630090, Russia
2 Institute of Coal and Coal Chemistry, Kemerovo 650616, Russia
3 JATIS, Sogo-kojimachi No. 3 Building, 1-6 Kojimachi, Chiyoda-ku, Tokyo 102-0086, Japan
4 Nippon Steel Corporation, 20-1 Shintomi, Futtsu, Chiba 293-8511, Japan

Funding (2)

1 Netherlands Organisation for Scientific Research
2 New Energy and Industrial Technology Development Organization

Abstract: The use of novel nanocarbon supports—carbon nanofibers (CNF) and amorphous supermicroporous carbons (ASC) for synthesis of platinum cathode catalysts for proton exchange membrane fuel cells (PEMFC) was investigated. Different types of CNF—with “parallel” and “deck of cards” arrangement of graphitic planes and samples of ASC originating from different organic precursors were synthesized and characterized by XRD, electron microscopy and adsorption methods. Platinum catalysts for PEMFC cathodes on different structural types of CNF and one sample of ASC were synthesized and characterized by XRD, electron microscopy, CO adsorption and by studying characteristics of conventional membrane electrode assembly (MEA) cell with a low Pt loading level of 0.02–0.09 mg/cm2. The MEA testing showed that the Pt cathode catalysts on CNF exhibit inferior performance in comparison with a catalyst on conventional carbon black support Pt/Vulcan XC-72R. The cathode catalyst prepared on ASC support exhibits considerably better output in MEA, compared with Pt/Vulcan XC-72R even at a lower Pt loading.
Cite: Ismagilov Z.R. , Kerzhentsev M.A. , Shikina N.V. , Lisitsyn A.S. , Okhlopkova L.B. , Barnakov C.N. , Sakashita M. , Iijima T. , Tadokoro K.
Development of Active Catalysts for Low Pt Loading Cathodes of PEMFC by Surface Tailoring of Nanocarbon Materials
Catalysis Today. 2005. V.102-103. P.58-66. DOI: 10.1016/j.cattod.2005.02.007 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Published online: Apr 22, 2005
Published print: May 15, 2005
Identifiers:
Web of science: WOS:000229823200010
Scopus: 2-s2.0-18844413226
Elibrary: 13476431
Chemical Abstracts: 2005:461930
Chemical Abstracts (print): 143:156223
OpenAlex: W2094186502
Citing:
DB Citing
Web of science 105
Scopus 105
Elibrary 124
OpenAlex 93
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