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Effect of Unsteady-State Catalyst Surface on the SCR-Process Full article

Conference 2nd International Symposium on the Dynamics of Catalytic Systems of the 12th International CHISA Congress
25-29 Aug 1996 , Prague
Journal Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308
Output data Year: 1997, Volume: 38, Number: 1, Pages: 97-105 Pages count : 9 DOI: 10.1016/S0920-5861(97)00043-6
Tags VANADIA-TITANIA CATALYSTS; PERIODIC-FLOW REVERSAL; MULTIPLE STEADY STATES; FIXED-BED REACTOR; DYNAMIC BEHAVIOR; NITRIC-OXIDE; REDUCTION; AMMONIA; OXIDATION; REGION
Authors Borisova E.S. 1 , Noskov A.S. 1 , Bobrova L.N. 1
Affiliations
1 Boreskov Institute of Catalysis, Prospekt Akademika Lavrentieva 5, 630090 Novosibirsk, Russia

Abstract: The kinetic model of nitrogen oxides reduction by ammonia on vanadium-containing catalysts considering the dynamic character ammonia surface interaction with NOx, and oxygen served as a base of mathematical model of unsteady-state processes in the fixed catalyst bed. The theoretical analysis of the model helped to study the catalytic reactor behavior, when the stoichiometric ratio of reagents NOx/NH3 is disturbed. A distribution of adsorbed ammonia along the catalyst bed was studied as a function of time between the reverses of gas flow passing through the catalyst bed. The model allowed to describe qualitatively the high degrees (up to 99%) of gas conversion of NOx obtained using a large scale plant.
Cite: Borisova E.S. , Noskov A.S. , Bobrova L.N.
Effect of Unsteady-State Catalyst Surface on the SCR-Process
Catalysis Today. 1997. V.38. N1. P.97-105. DOI: 10.1016/S0920-5861(97)00043-6 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Published print: Oct 5, 1997
Published online: Apr 20, 1998
Identifiers:
Web of science: WOS:A1997YE37100012
Scopus: 2-s2.0-0041104402
Elibrary: 13275374
Chemical Abstracts: 1997:616348
Chemical Abstracts (print): 127:322237
OpenAlex: W1989984234
Citing:
DB Citing
Web of science 10
Scopus 13
Elibrary 14
OpenAlex 12
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