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Novel Microdesign of Oxidation Catalysts. Part 2. The Influence of Fluorination on the Catalytic Properties of Glass Crystal Microspheres Научная публикация

Конференция 3rd Workshop on C1-C3 Hydrocarbon Conversion : NATO Advanced Research Workshop
14-17 июл. 1997 , Красноярск
Журнал Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308
Вых. Данные Год: 1998, Том: 42, Номер: 3, Страницы: 273-277 Страниц : 5 DOI: 10.1016/S0920-5861(98)00102-3
Ключевые слова Deep oxidation, Fluorination, Methane, Microspheres, Oxidative coupling
Авторы Fomenko E.V. 1 , Kondratenko E.V. 2 , Sharonova O.M. 2 , Plekhanov V.P. 1 , Koshcheev S.V. 3 , Boronin A.I. 3 , Salanov A.N. 3 , Bajukov O.A. 4 , Anshits A.G. 2
Организации
1 Krasnoyarsk State Technical University, Kirenskii Str. 26, Krasnoyarsk 660074, Russia
2 Institute of Chemistry of Natural Organic Materials, K. Marx Str. 42, Krasnoyarsk 660049, Russia
3 Boreskov Institute of Catalysis, Lavrent`ev Str. 5, Novosibirsk, Russia
4 Institute of Physics, Akademgorodok, Krasnoyarsk 660036, Russia

Реферат: New catalysts designed as glass crystal microspheres were studied by XPS, SEM, XRD and Mossbauer spectroscopy. The data obtained indicated that after treatment of catalysts with HF the fluorination of lattice took place leading to stabilization of Fe3O4 phase. The catalytic activity of initial catalysts and catalysts already treated with HF in the reactions of deep oxidation and oxidative coupling of methane was determined. The yield of C2-products at 1123 K was 16% for oxyfluoride systems using the gas mixture CH4:O2=85:15 vol%.
Библиографическая ссылка: Fomenko E.V. , Kondratenko E.V. , Sharonova O.M. , Plekhanov V.P. , Koshcheev S.V. , Boronin A.I. , Salanov A.N. , Bajukov O.A. , Anshits A.G.
Novel Microdesign of Oxidation Catalysts. Part 2. The Influence of Fluorination on the Catalytic Properties of Glass Crystal Microspheres
Catalysis Today. 1998. V.42. N3. P.273-277. DOI: 10.1016/S0920-5861(98)00102-3 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Опубликована в печати: 9 июл. 1998 г.
Опубликована online: 29 июл. 1998 г.
Идентификаторы БД:
Web of science: WOS:000075071900015
Scopus: 2-s2.0-0001499985
РИНЦ: 13281445
Chemical Abstracts: 1998:423681
Chemical Abstracts (print): 129:111128
OpenAlex: W2014830415
Цитирование в БД:
БД Цитирований
Web of science 22
Scopus 19
РИНЦ 28
OpenAlex 25
Альметрики: