Cu+(H2) and Na+(H2) Adducts in Exchanged ZSM-5 Zeolites | Sciact - CRIS-system of Boreskov Institute of Catalysis

Cu+(H2) and Na+(H2) Adducts in Exchanged ZSM-5 Zeolites Full article

Journal

Chemical Communications
ISSN: 1359-7345 , E-ISSN: 1364-548X

Output data

Year: 2004, Volume: 10, Number: 23, Pages: 2768-2769 Pages count : 2 DOI: 10.1039/b411053f

Tags

CARBON-MONOXIDE; IR; Cu-I-ZSM-5; ADSORPTION; COMPLEXES; ENERGIES; CLUSTERS; HYDROGEN; FTIR; H-2

Authors

Spoto Giuseppe ^1,2 , Gribov Evgueni ¹ , Bordiga Silvia ^1,2 , Lamberti Carlo ^1,2 , Ricchiardi Gabriele ^1,2 , Scarano Domenica ^1,2 , Zecchina Adriano ^1,2

Affiliations

1	Dipartimento di Chimica IFM, Via P. Giuria 7, I-10125 Torino, Italy
2	NIS – Nanostructured Interfaces and Surfaces – Centre of Excellence, c/o Dipartimento di Chimica IFM

Cu(I) ions in Cu-ZSM-5 form Cu+(H2) complexes, stable at room temperature and sub-atmospheric H2 pressure, which do not have any homogeneous analogue except for matrix-isolated [Cu(η2-H2)Cl]. Comparison with the unstable Na+(H2) adducts formed in the parent Na-ZSM-5 zeolite allow the conclusion that the Cu(I)/H2 bond is governed by σ–π overlap forces.

Spoto G. , Gribov E. , Bordiga S. , Lamberti C. , Ricchiardi G. , Scarano D. , Zecchina A.
Cu+(H2) and Na+(H2) Adducts in Exchanged ZSM-5 Zeolites
Chemical Communications. 2004. V.10. N23. P.2768-2769. DOI: 10.1039/b411053f WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Jul 20, 2004
Accepted:	Sep 7, 2004
Published online:	Oct 6, 2004
Published print:	Dec 4, 2004

Web of science:	WOS:000225377100060
Scopus:	2-s2.0-11144269087
Elibrary:	14564371
Chemical Abstracts:	2004:1037552
Chemical Abstracts (print):	142:184153
OpenAlex:	W2149834391

DB	Citing
Web of science	59
Scopus	60
OpenAlex	57