Synthesis of New Chiral Phosphorous- and Nitrogen-Containing Ligands From Resin Acids | Sciact - CRIS-система Института катализа

Synthesis of New Chiral Phosphorous- and Nitrogen-Containing Ligands From Resin Acids Научная публикация

Журнал

Chirality
ISSN: 0899-0042 , E-ISSN: 1520-636X

Вых. Данные

Год: 2004, Том: 16, Номер: SUPPL., Страницы: S40-S50 Страниц : 1 DOI: 10.1002/chir.20045

Ключевые слова

Asymmetric catalysis, Bisphosphines, Dehydroabietic acid, Diterpenes, Levopimaric acid, Thioureas, Ureas

Авторы

Khlebnikova Tatiana B. ¹ , Karpyshev Nikolay N. ¹ , Tolstikova Olga V. ² , Tolstikov Alexander G. ^1,2

Организации

1	Boreskov Institute of Catalysis, Siberian Branch of Russian Academy of Sciences, Novosibirsk, Russia
2	Institute of Technical Chemistry Ural’s Branch of Russian Academy of Sciences, Perm, Russia

Информация о финансировании (3)

1	Российский фонд фундаментальных исследований	04-03-32425
2	Российский фонд фундаментальных исследований	04-03-32063
3	Совет по грантам Президента Российской Федерации	НШ-2020.2003.3

Starting from the phytogenic diterpenes, chiral phosphine, urea, and thiourea derivatives were synthesized. Using these new chiral ligands, Rh(I) and Ru(II) complexes were prepared and used as catalysts for the catalytic asymmetric hydrogenation of unsaturated carboxylic acids and asymmetric hydrogen-transfer reduction of carbonyl compounds. Although the enantiopurity of the products obtained was not high, it was demonstrated that chiral ligands derived from diterpenes could be used for asymmetric reduction.

Khlebnikova T.B. , Karpyshev N.N. , Tolstikova O.V. , Tolstikov A.G.
Synthesis of New Chiral Phosphorous- and Nitrogen-Containing Ligands From Resin Acids
Chirality. 2004. V.16. NSUPPL.. P.S40-S50. DOI: 10.1002/chir.20045 WOS Scopus РИНЦ OpenAlex CAPlusCA PMID

Поступила в редакцию:	21 окт. 2003 г.
Принята к публикации:	23 февр. 2004 г.
Опубликована online:	25 июн. 2004 г.

≡ Web of science:	WOS:000222912900007
≡ Scopus:	2-s2.0-3242671481
≡ РИНЦ:	13452337
≡ OpenAlex:	W2074454493
≡ Chemical Abstracts:	2004:611323
≡ Chemical Abstracts (print):	141:395681
≡ PMID (PubMed):	15239072

≡ Web of science	14	Сбор данных от 20.02.2026
≡ Scopus	16	Сбор данных от 15.02.2026
≡ РИНЦ	19	Сбор данных от 15.02.2026
≡ OpenAlex	15	Сбор данных от 15.02.2026