Constitution and Properties of Nanocomposites Prepared by Thermal Decomposition of Silver Salts Sorbed by Polyacrylate Matrix Full article
| Journal |
Colloid Journal of the Russian Academy of Sciences: Kolloidnyi Zhurnal
ISSN: 1061-933X , E-ISSN: 1608-3067 |
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| Output data | Year: 2003, Volume: 65, Number: 6, Pages: 720-725 Pages count : 6 DOI: 10.1023/B:COLL.0000009114.41583.24 | ||||||||
| Tags | Oxygen Atom; Thermal Decomposition; Sorb; Silver Nitrate; Silver Particle | ||||||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | The Ministry of Education and Science of the Russian Federation | Ч0069 |
Abstract:
Constitution and dispersity of the products of thermal decomposition of silver nitrate ammonia complex sorbed by polyacrylate matrix are studied by the methods of small- and wide-angle X-ray scattering, optical, photoelectron and Auger-electron spectroscopies. It is shown that, at temperatures of 140–150°C, the complete decomposition of the complex occurs with the formation of nanoparticles and charged silver clusters in polymer bulk. No initial or intermediate products were observed. The average size of obtained nanoparticles is equal to 5 nm. The particles with the size less than 5 nm are amorphous according to X-ray data. The stabilization of nanoparticles occurs due to the adsorption of acrylic copolymer (presumably, via oxygen atoms) on their surfaces. Upon long-term storage in air, the self-diffusion of silver particles and clusters takes place from the surface to composite bulk caused by the detachment of oxygen-containing groups occurring at the metal–polymer interface.
Cite:
Izaak T.I.
, Babkina O.V.
, Boronin A.I.
, Drebushhak T.N.
, Stadnichenko A.I.
, Mokrousov G.M.
Constitution and Properties of Nanocomposites Prepared by Thermal Decomposition of Silver Salts Sorbed by Polyacrylate Matrix
Colloid Journal of the Russian Academy of Sciences: Kolloidnyi Zhurnal. 2003. V.65. N6. P.720-725. DOI: 10.1023/B:COLL.0000009114.41583.24 WOS Scopus РИНЦ ANCAN OpenAlex
Constitution and Properties of Nanocomposites Prepared by Thermal Decomposition of Silver Salts Sorbed by Polyacrylate Matrix
Colloid Journal of the Russian Academy of Sciences: Kolloidnyi Zhurnal. 2003. V.65. N6. P.720-725. DOI: 10.1023/B:COLL.0000009114.41583.24 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Изаак Т.И.
, Бабкина О.В.
, Боронин А.И.
, Дребущак Т.Н.
, Стадниченко А.И.
, Мокроусов Г.М.
Состав и свойства нанокомпозитов, полученных термическим разложением солей серебра, сорбированных полиакрилатной матрицей
Коллоидный журнал. 2003. Т.65. №6. С.788-794. РИНЦ
Состав и свойства нанокомпозитов, полученных термическим разложением солей серебра, сорбированных полиакрилатной матрицей
Коллоидный журнал. 2003. Т.65. №6. С.788-794. РИНЦ
Dates:
| Submitted: | Feb 10, 2003 |
| Published print: | Nov 1, 2003 |
Identifiers:
| Web of science: | WOS:000187805100009 |
| Scopus: | 2-s2.0-1642576990 |
| Elibrary: | 13436073 |
| Chemical Abstracts: | 2003:984662 |
| Chemical Abstracts (print): | 140:310200 |
| OpenAlex: | W2026276562 |