Selective Low-Temperature Transformation of Methane into C2-C4 Alkenes in the Presence of a Hydrogen-Accumulating System | Sciact - CRIS-system of Boreskov Institute of Catalysis

Selective Low-Temperature Transformation of Methane into C2-C4 Alkenes in the Presence of a Hydrogen-Accumulating System Full article

Journal

Doklady Physical Chemistry
ISSN: 0012-5016 , E-ISSN: 1608-3121

Output data

Year: 1998, Volume: 361, Number: 4-6, Pages: 276-279 Pages count : 4

Authors

Tsodikov M.V. ¹ , Slivinskii E.V. ¹ , Mordovin V.P. ¹ , Shestakov A.F. ¹ , Kochubey D.I. ¹ , Ivanov V.P. ¹ , Bukhtenko O.V. ¹ , Navío J. ¹

Affiliations

1	Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninskii pr. 29

Low-temperature conversion of CH4 in alkenes in the presence of H-accumulating system able to activate C-H bonds with subsequent removal of H from the reaction mixture was studied. The catalyst was a mixture of cylinders of highly purified Ti containing 0.4% wt. Ni and chips of highly purified Ti. The catalyst was activated by thermal treatment. Mechanism of formation of olefins is discussed. Conversion of methane at low temperature was 20% wt.; olefin content was 68-73% from it. 50-55% Wt. of all olefins was ethylene.

Tsodikov M.V. , Slivinskii E.V. , Mordovin V.P. , Shestakov A.F. , Kochubey D.I. , Ivanov V.P. , Bukhtenko O.V. , Navío J.
Selective Low-Temperature Transformation of Methane into C2-C4 Alkenes in the Presence of a Hydrogen-Accumulating System
Doklady Physical Chemistry. 1998. V.361. N4-6. P.276-279. Scopus РИНЦ

Цодиков М.В. , Сливинский Е.В. , Мордовин В.П. , Шестаков А.Ф. , Кочубей Д.И. , Иванов В.П. , Бухтенко О.В. , Навио Х.А.
Селективное низкотемпературное превращение метана в алкены C2-C4 в присутствии водородаккумулирующей системы
Доклады Академии наук. 1998. Т.361. №6. С.791-794. РИНЦ ANCAN

Submitted:	Feb 11, 1998
Published print:	Aug 1, 1998

Scopus:	2-s2.0-27144496180
Elibrary:	13281071

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