Sciact
  • EN
  • RU

The Influence of Support on the Low-Temperature Activity of Pd in the Reaction of CO Oxidation: 1. The Structure of Supported Pd Научная публикация

Журнал Journal of Catalysis
ISSN: 0021-9517 , E-ISSN: 1090-2694
Вых. Данные Год: 1996, Том: 161, Номер: 2, Страницы: 500-506 Страниц : 7 DOI: 10.1006/jcat.1996.0211
Ключевые слова CATALYTIC-OXIDATION; CARBON-MONOXIDE; PALLADIUM; EXAFS; RECONSTRUCTION; PARTICLES
Авторы Kochubey D.I. 1 , Pavlova S.N. 1 , Novgorodov B.N. 1 , Kryukova G.N. 1 , Sadykov V.A. 1
Организации
1 Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences

Реферат: The morphology of small Pd clusters on SiO2, TiO2, and Al2O3and the influence of CO and the reaction mixture CO + O2on their fine structure have been investigated by TEM and EXAFS. For all supports, Pd particles have a quite narrow size distribution with mean diameters in the range 15–25 Å, whereas their morphology and spatial homogeneity of location on the support are different. EXAFS data acquired in controlled-atmosphere cells have shown distortion of Pd surface layers to depend upon the nature of the support and/or the adsorbate. Disordering of Pd surface structure suggests appearance of the defect centers of CO and oxygen adsorption.
Библиографическая ссылка: Kochubey D.I. , Pavlova S.N. , Novgorodov B.N. , Kryukova G.N. , Sadykov V.A.
The Influence of Support on the Low-Temperature Activity of Pd in the Reaction of CO Oxidation: 1. The Structure of Supported Pd
Journal of Catalysis. 1996. V.161. N2. P.500-506. DOI: 10.1006/jcat.1996.0211 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 21 мар. 1994 г.
Принята к публикации: 24 янв. 1996 г.
Опубликована в печати: 1 июл. 1996 г.
Опубликована online: 25 мая 2002 г.
Идентификаторы БД:
Web of science: WOS:A1996VC88000002
Scopus: 2-s2.0-0001294035
РИНЦ: 13238214
Chemical Abstracts: 1996:504563
Chemical Abstracts (print): 125:149712
OpenAlex: W2001195029
Цитирование в БД:
БД Цитирований
Web of science 37
Scopus 41
РИНЦ 40
OpenAlex 42
Альметрики: