Abstract: Adsorption properties of Pd supported on γ-Al2O3, TiO2, SiO2, and adsorbed CO and oxygen low-temperature reactivities have been studied using IR spectroscopy, TPD, and pulse titration techniques. The results obtained are compared with the Pd surface structure data. At saturation coverages, weakly bound forms of CO (both linear and bridge-bonded) are the most reactive, their properties depending upon the type of support. Effect of Pd surface layer rearrangement due to CO and/or oxygen adsorption has also been found to be of importance. For mixed carbon monoxide–oxygen adlayer (θCO and θO are comparable), an overall Pd surface disordering occurs to wipe out all support effects.

Cite: Pavlova S.N. , Sadykov V.A. , Razdobarov V.A. , Paukshtis E.A.
The Influence of Support on the Low-Temperature Activity of Pd in the Reaction of CO Oxidation: 2. Adsorption Properties and Reactivity of Adsorbed Species
Journal of Catalysis. 1996. V.161. N2. P.507-516. DOI: 10.1006/jcat.1996.0212 WOS Scopus РИНЦ ANCAN OpenAlex

Dates:

Submitted:	Sep 21, 1994
Accepted:	Jan 24, 1996
Published print:	Jul 1, 1996
Published online:	May 25, 2002

Identifiers:

Web of science:	WOS:A1996VC88000003
Scopus:	2-s2.0-0001260131
Elibrary:	13233252
Chemical Abstracts:	1996:504564
Chemical Abstracts (print):	125:149713
OpenAlex:	W154589103

Citing:

DB	Citing
Web of science	36
Scopus	36
Elibrary	37
OpenAlex	28

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