Oxygen Adsorption on Ag(111): X-Ray Photoelectron Spectroscopy (XPS), Angular Dependent X-Ray Photoelectron Spectroscopy (ADXPS) and Temperature-Programmed Desorption (TPD) Studies Full article
| Journal |
Journal of Chemical Physics
ISSN: 0021-9606 , E-ISSN: 1089-7690 |
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| Output data | Year: 1999, Volume: 111, Number: 5, Pages: 2169-2175 Pages count : 7 DOI: 10.1063/1.479488 | ||
| Tags | ETHYLENE EPOXIDATION; SILVER; SURFACE; OXIDATION; CHEMISORPTION; MECHANISM; PRESSURE; MODEL; CO2; UPS | ||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Russian Foundation for Basic Research | 96-03-33891 |
| 2 | Siberian Branch of the Russian Academy of Sciences |
Abstract:
The O2 adsorption on Ag(111) single crystal in the range of 300–500 K has been studied by XPS, ADXPS, and TPD. At room temperature, the O1s line observed at 530.0 eV goes down to 528.2 eV when the sample is heated to 420 K. The comparison of XPS and TPD data indicates that both lines can be assigned to chemisorbed atomic oxygen. The depth concentration profiles calculated on the basis of the angular-dependent XPS data show that the line at 530.0 eV is responsible for oxygen adsorbed at the surface, as opposed to that at 528.2 eV which is assigned to oxygen between the top and second silver layers. The formation of surface silver oxide is concluded in the latter case.
Cite:
Bukhtiyarov V.I.
, Kaichev V.V.
, Prosvirin I.P.
Oxygen Adsorption on Ag(111): X-Ray Photoelectron Spectroscopy (XPS), Angular Dependent X-Ray Photoelectron Spectroscopy (ADXPS) and Temperature-Programmed Desorption (TPD) Studies
Journal of Chemical Physics. 1999. V.111. N5. P.2169-2175. DOI: 10.1063/1.479488 WOS Scopus РИНЦ ANCAN OpenAlex
Oxygen Adsorption on Ag(111): X-Ray Photoelectron Spectroscopy (XPS), Angular Dependent X-Ray Photoelectron Spectroscopy (ADXPS) and Temperature-Programmed Desorption (TPD) Studies
Journal of Chemical Physics. 1999. V.111. N5. P.2169-2175. DOI: 10.1063/1.479488 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Oct 16, 1998 |
| Accepted: | Apr 21, 1999 |
| Published online: | Jul 20, 1999 |
| Published print: | Aug 1, 1999 |
Identifiers:
| Web of science: | WOS:000081698700045 |
| Scopus: | 2-s2.0-0000960158 |
| Elibrary: | 13316545 |
| Chemical Abstracts: | 1999:444147 |
| Chemical Abstracts (print): | 131:175424 |
| OpenAlex: | W2039473425 |