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Application of Differential Charging for Analysis of Electronic Properties of Supported Silver Научная публикация

Журнал Journal of Electron Spectroscopy and Related Phenomena
ISSN: 0368-2048 , E-ISSN: 1873-2526
Вых. Данные Год: 1996, Том: 77, Номер: 1, Страницы: 7-14 Страниц : 8 DOI: 10.1016/0368-2048(95)02378-X
Ключевые слова Ag(111), Binding energy, Conductivity, Differential charging, Ethylene, Silver, X-ray photoelectron spectroscopy
Авторы Bukhtiyarov V.I. 1 , Prosvirin I.P. 1 , Kvon R.I. 1
Организации
1 Boreskov Institute of Catalysis

Реферат: The electronic properties of silver supported on α-alumina (ethylene epoxidation catalysts) have been studied by X-ray photoelectron spectroscopy. It has been shown that treatment of the fresh catalyst in C2H4 + O2 reaction mixture increases the Full-size image (<1 K) core level binding energy (BE). The observed variation of the Full-size image (<1 K) does not reflect a change in the initial state of silver from metallic, but is determined by the alteration in the differential charging of the supported silver compared with the support surface. The latter effect originates from the higher conductivity of the supported silver than of the dielectric support. Possible factors affecting the internal conductivity of the silver are discussed.
Библиографическая ссылка: Bukhtiyarov V.I. , Prosvirin I.P. , Kvon R.I.
Application of Differential Charging for Analysis of Electronic Properties of Supported Silver
Journal of Electron Spectroscopy and Related Phenomena. 1996. V.77. N1. P.7-14. DOI: 10.1016/0368-2048(95)02378-X WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 21 апр. 1994 г.
Принята к публикации: 26 июн. 1995 г.
Опубликована в печати: 1 февр. 1996 г.
Опубликована online: 31 авг. 1998 г.
Идентификаторы БД:
Web of science: WOS:A1996UE52900002
Scopus: 2-s2.0-0030087116
РИНЦ: 13240019
Chemical Abstracts: 1996:251704
Chemical Abstracts (print): 124:326119
OpenAlex: W2022767326
Цитирование в БД:
БД Цитирований
Web of science 27
Scopus 29
РИНЦ 31
OpenAlex 21
Альметрики: