Synthesis of Carbon-Coated MgO Nanoparticles | Sciact - CRIS-system of Boreskov Institute of Catalysis

Synthesis of Carbon-Coated MgO Nanoparticles Full article

Journal

Journal of Materials Chemistry (up to 2012)
ISSN: 0959-9428 , E-ISSN: 1364-5501

Output data

Year: 2002, Volume: 12, Number: 12, Pages: 3599-3604 Pages count : 6 DOI: 10.1039/b207972k

Tags

chlorobutane; butane; carbon; inert gas; magnesium hydroxide; magnesium oxide; metal oxide; resorcinol; sulfide; unclassified drug; water

Authors

Bedilo Alexander F. ¹ , Sigel M.Jake ² , Koper Olga B. ² , Melʹgunov Maxim S. ^1,3 , Klabunde Kenneth J. ^1,2

Affiliations

1	Department of Chemistry, Kansas State University, Manhattan, Kansas, USA 66506
2	Nanoscale Materials, Inc., Manhattan, Kansas, USA 66502
3	Boreskov Institute of Catalysis, Novosibirsk, Russia 630090

Carbon-coated MgO nanoparticles, with carbon forming a porous coating on the surface of MgO nanoparticles, have been prepared by two different techniques. Resorcinol has been found to be an efficient agent for the modification of magnesium methoxide leading to carbon-coated MgO nanocrystals of small crystallite size and high surface area. Decomposition of dry magnesium methoxide under an inert gas flow proved to be another efficient and economical way to synthesise carbon-coated MgO. The carbon coating acts as a hydrophobic barrier partially protecting the core metal oxide from water adsorption and conversion to magnesium hydroxide. However, destructive adsorption reactions can still proceed on the metal oxide surface, as evidenced by the dehydrochlorination of 2-chloroethyl ethyl sulfide (2-CEES) and 1-chlorobutane. The overall stability of the material in the presence of water vapor is significantly improved in comparison with non-coated nanocrystalline MgO.

Bedilo A.F. , Sigel M.J. , Koper O.B. , Melʹgunov M.S. , Klabunde K.J.
Synthesis of Carbon-Coated MgO Nanoparticles
Journal of Materials Chemistry (up to 2012). 2002. V.12. N12. P.3599-3604. DOI: 10.1039/b207972k WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Aug 14, 2002
Accepted:	Aug 20, 2002
Published online:	Nov 5, 2002
Published print:	Nov 29, 2002

Web of science:	WOS:000179554700040
Scopus:	2-s2.0-0036926514
Elibrary:	13407144
Chemical Abstracts:	2002:910661
Chemical Abstracts (print):	138:174329
OpenAlex:	W2068251775

DB	Citing
Web of science	48
Scopus	49
Elibrary	50
OpenAlex	51