EPR and H1 NMR Spectroscopic Characterization of the Ferric Species Formed in the Iron Picolinate/(pyridine/acetic acid)/HOOH Catalytic System for the Direct Ketonization of Methylenic Carbons Full article
| Journal |
Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169 |
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| Output data | Year: 1996, Volume: 112, Number: 2, Pages: 253-258 Pages count : 6 DOI: 10.1016/1381-1169(96)00153-7 | ||||
| Tags | Cyclohexane, EPR, Ferric peroxo complexes, NMR, Oxidation | ||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union | 94-1515 |
| 2 | Russian Foundation for Basic Research | 93-03-4758 |
Abstract:
Using EPR and H1 NMR spectroscopy, ferric species formed in the iron picolinate/(pyridine/acetic acid)/HOOH catalytic system for the direct ketonization of methylenic carbons were characterized. The initial complex K[FeII(PA)3] (PA-pyridine-2-carboxylato) converts into mononuclear hydroxo complex FeIII(PA)2(OH)Py via interaction with equimolar amount of HOOH in 2:1 Py/AcOH molar mixture. Addition of the great excess of HOOH to the solution of FeIII(PA)2(OH)Py in 2:1 Py/AcOH at 253 K gives rise to the formation of the unstable high-spin ferric peroxo complex with suggested structure FeIII(PA)2(OOH)Py. This complex is supposed to be reactive intermediate of oxidation.
Cite:
Sobolev A.P.
, Babushkin D.E.
, Shubin A.A.
, Talsi E.P.
EPR and H1 NMR Spectroscopic Characterization of the Ferric Species Formed in the Iron Picolinate/(pyridine/acetic acid)/HOOH Catalytic System for the Direct Ketonization of Methylenic Carbons
Journal of Molecular Catalysis A: Chemical. 1996. V.112. N2. P.253-258. DOI: 10.1016/1381-1169(96)00153-7 WOS Scopus РИНЦ ANCAN OpenAlex
EPR and H1 NMR Spectroscopic Characterization of the Ferric Species Formed in the Iron Picolinate/(pyridine/acetic acid)/HOOH Catalytic System for the Direct Ketonization of Methylenic Carbons
Journal of Molecular Catalysis A: Chemical. 1996. V.112. N2. P.253-258. DOI: 10.1016/1381-1169(96)00153-7 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Feb 19, 1996 |
| Accepted: | Mar 19, 1996 |
| Published print: | Oct 25, 1996 |
| Published online: | Oct 7, 1998 |
Identifiers:
| Web of science: | WOS:A1996VN81000010 |
| Scopus: | 2-s2.0-0030601551 |
| Elibrary: | 18252771 |
| Chemical Abstracts: | 1996:609267 |
| Chemical Abstracts (print): | 125:309873 |
| OpenAlex: | W2090699786 |