Abstract: The interaction of the supported catalyst based on the organic nickel chelate compound (I) with carbon monoxide and deuterated ethylene has been studied using IRS–DS. The surface nickel compound (SNC) interacts with carbon monoxide in the same manner as the initial nickel complex (I). The reaction of SNC or nickel complex (I) with CO yields nickel acyl complex (V) (a product of the CO insertion into the Ni–Ph bond), ester (VIII) and various nickel carbonyls (VI). According to the IRS data, the interaction between SNC and deuterated ethylene gives a polymer. The subsequent carbon monoxide introduction results in the same products as in the case of the CO reaction with SNC. The interaction between ethylene and SNC pretreated with carbon monoxide does not lead to polymerization.

Cite: Panchenko V.N. , Zakharov V.A. , Paukshtis E.A.
The IRS-DR Study of Interaction of the Supported Catalyst Based on the Organic Nickel Chelate with Carbon Monoxide and Ethylene
Journal of Molecular Catalysis A: Chemical. 1998. V.135. N2. P.115-120. DOI: 10.1016/S1381-1169(97)00300-2 WOS Scopus РИНЦ ANCAN OpenAlex

Dates:

Submitted:	Mar 15, 1997
Accepted:	Nov 21, 1997
Published online:	Oct 13, 1998
Published print:	Oct 14, 1998

Identifiers:

Web of science:	WOS:000076564300001
Scopus:	2-s2.0-0032517328
Elibrary:	13297357
Chemical Abstracts:	1998:626692
Chemical Abstracts (print):	130:66829
OpenAlex:	W2000223385

Citing:

DB	Citing
Web of science	2
Scopus	2
Elibrary	2
OpenAlex	1

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