Models of (ZrO2)n Complexes Intercalated into Montmorillonite Full article
| Journal |
The Journal of Physical Chemistry B
ISSN: 1520-6106 , E-ISSN: 1520-5207 |
||
|---|---|---|---|
| Output data | Year: 2005, Volume: 109, Number: 15, Pages: 7451-7459 Pages count : 9 DOI: 10.1021/jp045100w | ||
| Tags | Absorption spectroscopy; Additives; Adsorption isotherms; Calcination; Clay; Complexation; Monte Carlo methods; Silicates; Synthesis (chemical); X ray diffraction analysis | ||
| Authors |
|
||
| Affiliations |
|
Funding (1)
| 1 | Президиум РАН | 8.23 |
Abstract:
The article discusses the properties of several model zirconium dioxide complexes (ZrO2)n intercalated into the interlayer space of montmorillonite clay. Grand canonical Monte Carlo simulation was used in a series of numerical experiments during analysis of the low-temperature nitrogen adsorption in the micropores thus generated. The goal of such experiments was to determine the geometrical parameters of introduced molecular complexes of different types inside micropores of various widths. The obtained information was used to characterize textural and structural properties of three pillared interlayer materials prepared by using pillaring species synthesized via aging of zirconyl chloride solutions containing as additives chlorides of Ca, Sr, or Ba. It was found that in the cases of Ba and Ca the interlayer micropores are filled with isolated tetramers (ZrO2)4. Meanwhile, the presence of Sr in the pillaring solution, most likely, favors the preservation of larger sheetlike complexes (ZrO2)8.
Cite:
Efremov D.
, Kuznetsova T.
, Doronin V.
, Sadykov V.
Models of (ZrO2)n Complexes Intercalated into Montmorillonite
The Journal of Physical Chemistry B. 2005. V.109. N15. P.7451-7459. DOI: 10.1021/jp045100w WOS Scopus РИНЦ ANCAN PMID OpenAlex
Models of (ZrO2)n Complexes Intercalated into Montmorillonite
The Journal of Physical Chemistry B. 2005. V.109. N15. P.7451-7459. DOI: 10.1021/jp045100w WOS Scopus РИНЦ ANCAN PMID OpenAlex
Dates:
| Submitted: | Oct 27, 2004 |
| Accepted: | Feb 17, 2005 |
| Published online: | Mar 26, 2005 |
| Published print: | Apr 1, 2005 |
Identifiers:
| Web of science: | WOS:000228419100076 |
| Scopus: | 2-s2.0-17844369483 |
| Elibrary: | 13487247 |
| Chemical Abstracts: | 2005:263446 |
| Chemical Abstracts (print): | 142:488052 |
| PMID: | 16851854 |
| OpenAlex: | W1987681722 |