Changes in Texture and Catalytic Activity of Nanocrystalline MgO during Its Transformation to MgCl2 in the Reaction with 1-Chlorobutane | Sciact - CRIS-system of Boreskov Institute of Catalysis

Changes in Texture and Catalytic Activity of Nanocrystalline MgO during Its Transformation to MgCl2 in the Reaction with 1-Chlorobutane Full article

Journal

The Journal of Physical Chemistry B
ISSN: 1520-6106 , E-ISSN: 1520-5207

Output data

Year: 2001, Volume: 105, Number: 18, Pages: 3937-3941 Pages count : 5 DOI: 10.1021/jp0039969

Tags

ULTRAFINE NANOSCALE PARTICLES; METAL-OXIDE PARTICLES; DESTRUCTIVE ADSORPTION; CHLORINATED HYDROCARBONS; CALCIUM-OXIDE; SURFACE-CHEMISTRY; MAGNESIUM-OXIDE; REAGENTS

Authors

Fenelonov Vladimir B. ¹ , Mel'gunov Maxim S. ¹ , Mishakov Ilya V. ¹ , Richards Ryan M. ² , Chesnokov Vladimir V. ¹ , Volodin Alexander M. ¹ , Klabunde Kenneth J. ²

Affiliations

1	Boreskov Institute of Catalysis, Novosibirsk 630090, Russia
2	Department of Chemistry, Kansas State University, Manhattan, Kansas 66506

The interaction of 1-chlorobutane with nanocrystalline MgO at 200−350 °C has been found to result in both stoichiometric and catalytic dehydrochlorination of 1-chlorobutane to isomers of butene and simultaneous topochemical conversion of MgO to MgCl2. The obtained magnesium chloride appeared to be an active catalyst for the dehydrochlorination reaction, so the rate of 1-chlorobutane conversion grows significantly with time. Changes in the MgO texture during the topochemical reaction are discussed and their effect on the catalytic activity is estimated.

Fenelonov V.B. , Mel'gunov M.S. , Mishakov I.V. , Richards R.M. , Chesnokov V.V. , Volodin A.M. , Klabunde K.J.
Changes in Texture and Catalytic Activity of Nanocrystalline MgO during Its Transformation to MgCl2 in the Reaction with 1-Chlorobutane
The Journal of Physical Chemistry B. 2001. V.105. N18. P.3937-3941. DOI: 10.1021/jp0039969 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Oct 27, 2000
Published online:	Mar 16, 2001
Published print:	May 1, 2001

Web of science:	WOS:000168624400036
Scopus:	2-s2.0-0035838005
Elibrary:	41817546
Chemical Abstracts:	2001:180154
Chemical Abstracts (print):	134:366459
OpenAlex:	W2046307915

DB	Citing
Web of science	22
Scopus	28
Elibrary	27
OpenAlex	32