Реферат: High-pressure CO adsorption on Pd(111) was examined by X-ray photoelectron spectroscopy (XPS) and vibrational sum frequency generation (SFG) from 200 to 400 K, and in a pressure range from 10-6 to 1 mbar. Even in the millibar regime both methods indicated that CO adsorbed in “regular” adsorption sites such as hollow, bridge, and on-top. By combination of XPS and SFG, a quantitative analysis of CO coverages at various pressures was performed. At high pressure, no CO structures different from those known from UHV studies were observed. Also, no indications of CO dissociation or carbonyl formation were found under the given experimental conditions, provided that the CO gas was sufficiently cleaned.

Библиографическая ссылка: Kaichev V.V. , Prosvirin I.P. , Bukhtiyarov V.I. , Unterhalt H. , Rupprechter G. , Freund H-J.
High-Pressure Studies of CO Adsorption on Pd(111) by X-ray Photoelectron Spectroscopy and Sum-Frequency Generation
The Journal of Physical Chemistry B. 2003. V.107. N15. P.3522-3527. DOI: 10.1021/jp021992t WOS Scopus РИНЦ CAPlusCA OpenAlex

Даты:

Поступила в редакцию:	6 сент. 2002 г.
Опубликована в печати:	1 апр. 2003 г.

Идентификаторы БД:

Web of science:	WOS:000182167500026
Scopus:	2-s2.0-0037451812
РИНЦ:	41796863
Chemical Abstracts:	2003:226968
Chemical Abstracts (print):	138:374494
OpenAlex:	W1980897511

Цитирование в БД:

БД	Цитирований
Web of science	90
Scopus	97
РИНЦ	94
OpenAlex	97

Альметрики: