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Structural Study of Bimetallic Catalytic Nanosystems Containing Precious Metals by XAFS Spectroscopy Conference attendances

Language Английский
Participant type Стендовый
Conference International Conference "Synchrotron and Free electron laser Radiation: generation and application"
13-17 Jul 2020 , Novosibirsk
Authors Kriventsov Vladimir Vladimirovich 1 , Volodin Alexander Mikhailovich 1 , Novgorodov Boris Nikolaevich 1 , Zyuzin Dmitriy Albertovich 1 , Aksenov Dmitry Grigorʹevich 1 , Ivanov Dmitrii Petrovich 1 , Iost Kristina Nikolaevna 2 , Shlyapin Dmitrii Andreevich 2 , Nikolaev Sergej Aleksandrovich 3 , Chistyakov Andrej Valerʹevich 4 , Tsodikov Mark Veniaminovich 4
Affiliations
1 Boreskov Institute of Catalysis SB RAS
2 Institute of Hydrocarbons Processing SB RAS
3 Lomonosov Moscow State University
4 A.V. Topchiev Institute of Petrochemical Synthesis RAS

Abstract: This work presents the results of a study of the local structure of the active component of mono-, bi-metallic low-percentage (~1%) catalysts (containing Pt, Au, Pd, Ru) stabilized on oxide carriers using XAFS method (XANES/EXAFS). Studying the nature of nano-forms of noble metal stabilization is promising for creating effective catalysts for various applications, including catalytic systems for alternative energy applications. The development of synthesis methods can lead to a significant economic gain, due to the reduction of the metal content and optimization of the catalytic properties of the system. Model catalysts were prepared from mono-and bimetallic complexes, with varying synthesis methods: sol-gel, ion exchange, impregnation, reducing modes, and the nature of carriers. XAFS (XANES/EXAFS) spectra (Pt-L3, Au-L3, Pd-K, Ru-K) of studied samples were recorded at SSTRC, Novosibirsk. Genesis of the local structure of the active component was studied, including the study of oxidized precursors and catalysts after reducing and activation. It is established that depending on the background, it is possible to form various nanoscale forms of noble metals localized on the surface of the oxide carrier. Additionally, the samples were studied by XRD, XPS, XRFA, HRTEM. Variants of possible structural models are considered in detail.
Cite: Kriventsov V.V. , Volodin A.M. , Novgorodov B.N. , Zyuzin D.A. , Aksenov D.G. , Ivanov D.P. , Iost K.N. , Shlyapin D.A. , Nikolaev S.A. , Chistyakov A.V. , Tsodikov M.V.
Structural Study of Bimetallic Catalytic Nanosystems Containing Precious Metals by XAFS Spectroscopy
International Conference "Synchrotron and Free electron laser Radiation: generation and application" 13-17 Jul 2020