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Probing Light Hydrocabons Mobility by 2H NMR in Nanoporous UiO-66 MOF: Effects of Inorganic Centers Hydroxylation and Framework Defecfs Conference attendances

Language Английский
Participant type Устный
Conference 15th International Bologna Conference on Magnetic Resonance in Porous Media
21-26 Aug 2022 , Hangzhou
Authors Khudozhitkov Alexander E. 1,2 , Steapanov Alexander G. 1 , Kolokolov Daniil I. 1,3
Affiliations
1 Boreskov Institute of Catalysis SB RAS
2 Novosibirsk National Research University
3 Rostock University

Abstract: The porous metal-organic frameworks (MOFs) are currently regarded as one of the main platforms for energy efficient solutions in such important industrial tasks as hydrocarbon mixtures separation, CO2 sequestration and heterogenous catalysis. These processes are greatly dependent on the guest-host interaction of the adsorbed species with the hosting framework. In case of MOFs the guest host interactions are influenced by the presence of active sites, like open metal centers, capable to form hydrogen bonds functional groups (i.e. OH species) and the potential presence of defects.
Cite: Khudozhitkov A.E. , Steapanov A.G. , Kolokolov D.I.
Probing Light Hydrocabons Mobility by 2H NMR in Nanoporous UiO-66 MOF: Effects of Inorganic Centers Hydroxylation and Framework Defecfs
15th International Bologna Conference on Magnetic Resonance in Porous Media 21-26 Aug 2022