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High Temperature WGSR Catalyst Based on the Nanodispersed Metastable Fe oxyhydroxide, 2-Line Ferrihydrite Conference attendances

Language Английский
Participant type Стендовый
Conference 9th Natural Gas Conversion Symposium
30 May - 3 Jun 2010 , Lyon
Authors Khassin A.A. 1 , Minyukova T.P. 1 , Baronskaya N.A. 1 , Filonenko G.A. 1 , Yurieva T.M. 1
Affiliations
1 Boreskov Institute of Catalysis SB RAS

Abstract: Cr, Cu-doped 2-line ferrihydrite (2-LFH) demonstrates high catalytic activity, especially at low temperature (300-350°C) that allows reducing the star ting temperature in adiabatic HT WGS reactor. Kinetic analysis data show that promotion of 2LFH by Me3+ cations can dramatically change the activation energy and the rate of crystallization to hematite. Metastability of Cr-promoted 2LFH and its transformation to hematite doesn’t restrict application of 2LFH in catalytic reactions at moderate temperatures.
Cite: Khassin A.A. , Minyukova T.P. , Baronskaya N.A. , Filonenko G.A. , Yurieva T.M.
High Temperature WGSR Catalyst Based on the Nanodispersed Metastable Fe oxyhydroxide, 2-Line Ferrihydrite
9th Natural Gas Conversion Symposium 30 May - 3 Jun 2010