Реферат: Ruddlesden – Popper phases are known materials for electrochemical devices such as solid oxide fuel cells/electrolyzers, oxygen separation membranes. Doping A-site with lanthanides with less radii can allow to increase the oxygen mobility, however, this problem is still not studied well. This work aims at studying structural and transport properties of Sm doped Nd nickelates sintered by radiation-thermal technique using e-beams. Nd2 xSmxNiO4+δ (x = 0.2, 0.4) were synthesized by modified Pechini technique and sintered by e-beams at 1150 – 1250 °C. The materials obtained were characterized by X-ray diffraction, X-ray photoelectron spectroscopy and temperature-programmed isotope exchange of oxygen with C18O2 in a flow reactor. The surface oxygen presents in two forms differing in binding energy. According to the temperature-programmed isotope exchange data, the samples possess nonuniformity in the oxygen mobility, and slow diffusion channel is present for the sample with x = 0.4. Such an oxygen diffusion features are probably related to the effect of doping with and radiation-thermal sintering on the structure with formation of admixed phases, hampering the cooperative migration due to emergence of local defects and variation of the surface layers composition. Keywords: solid oxide fuel cell, cathode, oxygen separation membrane, radiation-thermal sintering, Ruddlesden – Popper phases, Nd2NiO4, doping, isotope exchange of oxygen, oxygen mobility, self-diffusion.

Библиографическая ссылка: Sadykov V.A. , Sadovskaya E.M. , Bespalko Y.N. , Smal’ E.A. , Bulavchenko O.A. , Eremeev N.F. , Prosvirin I.P. , Mikhailenko M.A. , Korobeinikov M.V.
Oxygen Mobility of Samarium Doped Neodymium Nickelates Sintered by E-Beams
17th International Meeting “Fundamental and Applied Problems of Solid State Ionics” 16-23 Jun 2024