Реферат: The work presented in the paper is devoted to the development of the synthesis of the new chiral copper catalysts for nitroaldol condensation containing tetradentate ligands derived from natural terpenes. Novel chiral copper complexes with nitrogen-containing ligands catalyze the reaction of nitromethane with aldehydes to give nitroalcohol in yields of 45-99% and optical purity of 60% ee.

Библиографическая ссылка: Konev V.N. , Khlebnikova T.B. , Malysheva L.V. , Pai Z.P.
New Chiral Catalysts of Nitroaldol Condensation
EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources” 30 Aug - 4 Sep 2015