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Design of Ceramometal Cu-Al Catalyst with Egg-Shell Microstructure for Water-Gas Shift Reaction Conference attendances

Language Английский
Participant type Стендовый
Conference EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources”
30 Aug - 4 Sep 2015 , Казань
Authors Tikhov Serguei Fedorovich 1 , Minyukova Tatyana Petrovna 1 , Valeev Konstantin Radikovich 1 , Cherepanova Svetlana Vitalievna 1 , Salanov Aleksei Nikolaevich 1 , Kaichev Vasily Vasilievich 1 , Saraev Andrey Aleksandrovich 1 , Andreev Andrey Sergeevich 1 , Lapina Olga Borisovna 1 , Sadykov Vladislav Aleksandrovich 1,2 , Gerasimov Konstantin Borisovich 3
Affiliations
1 Boreskov Institute of Catalysis SB RAS
2 Novosibirsk National Research University
3 Institute of Solid State Chemistry and Mechanochemistry SB RAS

Abstract: Water-gas shift reaction (WGS) is one of the primary industrial reactions of hydrogen production. One of the main problem of low temperature shift is the low activity of conventional catalyst per volume of the catalyst bed. The possible way to increase the volume activity is the use of ceramometal catalysts with enhanced real and loading density. In the presented work a new CuAl-based catalyst prepared through the stage of mechanical alloying of Cu-Al powders was developed. The detailed study of the structural, textural, surface and other physical properties in comparison with catalytic properties of cermet CuAlO/CuAl catalysts has been carried out. It was found that TOF values of some cermet catalyst are higher than for conventional CuZnAl oxide catalyst. The structure sensitivity of cermets has been discussed
Cite: Tikhov S.F. , Minyukova T.P. , Valeev K.R. , Cherepanova S.V. , Salanov A.N. , Kaichev V.V. , Saraev A.A. , Andreev A.S. , Lapina O.B. , Sadykov V.A. , Gerasimov K.B.
Design of Ceramometal Cu-Al Catalyst with Egg-Shell Microstructure for Water-Gas Shift Reaction
EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources” 30 Aug - 4 Sep 2015