Study of Influence of cis-trans Isomerization on Selective Oxidations of Alkenes by Nitrous Oxide - Conference attendances | Sciact - CRIS-system of Boreskov Institute of Catalysis

Study of Influence of cis-trans Isomerization on Selective Oxidations of Alkenes by Nitrous Oxide Conference attendances

Language

Английский

Participant type

Стендовый

Conference

EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources”
30 Aug - 4 Sep 2015 , Казань

Authors

Ivanov Dmitrii Petrovich ¹ , Semikolenov Sergej Vladimirovich ¹ , Nartova Anna Vladimirovna ^1,2 , Fedorov Vladimir Sergeevich ^1,2 , Babushkin Dmitrii Eduardovich ¹ , Dubkov Konstantin Aleksandrovich ¹

Affiliations

1	Boreskov Institute of Catalysis SB RAS
2	Novosibirsk National Research University

In the present work the influence of cis-trans isomerization of heptane-3 on reactivity of C=C bond of alkenes towards N2O as well as the contribution of the reaction route with the break of the initial double bounds were studied. It was shown that both cis- and trans-heptane isomers perform very similar reactivity. At the same time for trans-hepten-3 the contribution of the route with C-C bound break is approximately three times higher comparing with cis-heptane-3. The study reveals the common regularities of the oxidation of compounds with C=C bounds by nitrous oxide. The observed difference in contribution of the reaction route with C-C bound break for the olefins confirms the results obtained for rubbers previously.

Ivanov D.P. , Semikolenov S.V. , Nartova A.V. , Fedorov V.S. , Babushkin D.E. , Dubkov K.A.
Study of Influence of cis-trans Isomerization on Selective Oxidations of Alkenes by Nitrous Oxide
EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources” 30 Aug - 4 Sep 2015