Abstract: In recent years there is appreciable progress in the solving of question on the reaction mechanism, generally due to development of isotopic-kinetic methods, particularly SSITKA technique (Steady-State Isotopic Transient Kinetic Analysis). This technique allows to reveal the main pathways of transformation of labeled reagents into reaction products directly under steady state reaction conditions [1,2]. In the lecture various methodological aspects of isotopic-kinetic experiments with SSITKA technique as well as mathematical modeling will be discussed. The results of investigation of partial oxidation over widely used vanadia-titania catalysts (VOX)n/TiO2 [3] as well as over novel multicomponent oxide catalysts Mo-V-Te-Nb [4] will be presented.

Cite: Sadovskaya E.M.
Isotopic-Kinetic Study of Reactivity of Surface Oxygen Species on Oxide Catalysts in Partial and Deep Hydrocarbon Oxidation
III International Scientific School-Conference for Young Scientists "Catalysis: from Science to Industry" 26-29 Oct 2014