Propylene Glycol Oxidation over Cr-MIL-101 with Tert-Butyl Hydroperoxide Доклады на конференциях
Язык | Английский | ||||
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Тип доклада | Стендовый | ||||
Конференция |
EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources” 30 авг. - 4 сент. 2015 , Казань |
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Ключевые слова | propylene glycol, metal-organic framework, selective oxidation, hydroxyacetone | ||||
Авторы |
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Организации |
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Реферат:
Propylene glycol can be produced from glycerol, which is a low-cost by-product in transesterification of triglycerides for biodiesel production. A number of valuable products that find application in the production of fine chemicals and pharmaceutics can be obtained through oxidation of 1,2-propylene glycol. The potential of the chromium terephthalate CrMIL-101 in the selective oxidation of propylene glycol under mild conditions (50-70°C) using tert-butyl hydroperoxide as oxidant was explored. The effects of reaction conditions (temperature, concentrations, solvent nature) on this reaction were evaluated. Hydroxyacetone was shown to be the predominant product. C-C cleavage, which is typical of PG oxidation, did not take place in the catalytic system studied. However, the oxidation products (for example, methyl glyoxal) could undergo non-oxidative transformations under the reaction conditions. Further work is in progress to clarify this matter.
Библиографическая ссылка:
Torbina V.
, Ivanchikova I.D.
, Kholdeeva O.A.
, Vodyankina O.V.
Propylene Glycol Oxidation over Cr-MIL-101 with Tert-Butyl Hydroperoxide
EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources” 30 Aug - 4 Sep 2015
Propylene Glycol Oxidation over Cr-MIL-101 with Tert-Butyl Hydroperoxide
EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources” 30 Aug - 4 Sep 2015