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Development of the Methods for Fast Catalytic Air Purification from CWAs Conference attendances

Language Английский
Participant type Стендовый
Conference EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources”
30 Aug - 4 Sep 2015 , Казань
Authors Kolinko Pavel Anatolevich 1,2 , Lyulyukin Mikhail Nikolaevich 1 , Besov Alexey Sergeevich 1,2 , Parkhomchuk Ekaterina Vasilievna 1,2,3 , Kozlov Denis Vladimirovich 1,2,3
Affiliations
1 Boreskov Institute of Catalysis SB RAS
2 Novosibirsk National Research University
3 Novosibirsk National Research University

Abstract: In today's world there is a high probability of terrorist attacks and technological disasters. The result is a deadly emission of dangerous organic vapors and aerosols. It is especially dangerous if it happens in the places of the people congestion. In our study, we propose the method of fast air and surfaces decontamination based on the fast adsorption with subsequent degradation of adsorbed CWA by the Fenton system. The butyl-β-chloroethylsulfide (BCES), dimethyl methylphosphonate (DMMP) and O, O-diethyl-O-3,4,5- trichlorophenylphosphate (DETCPP) have been chosen as the conventional imitators of mustard and organophosphorus CWAs. Adsorption experiments were conducted on the following adsorbents: TiO2, AlOOH, SiO2, MgO, Fe2O3. Purification of the surfaces from the CWA’s simulants takes less than 30 minutes with using of the heterogeneous Fenton system on Fe-ZSM-5 zeolite.
Cite: Kolinko P.A. , Lyulyukin M.N. , Besov A.S. , Parkhomchuk E.V. , Kozlov D.V.
Development of the Methods for Fast Catalytic Air Purification from CWAs
EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources” 30 Aug - 4 Sep 2015