Solvation Shell of Platinum Complexes in Solutions According to EXAFS Data - Conference attendances | Sciact - CRIS-system of Boreskov Institute of Catalysis

Solvation Shell of Platinum Complexes in Solutions According to EXAFS Data Conference attendances

Language

Английский

Participant type

Стендовый

Conference

EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources”
30 Aug - 4 Sep 2015 , Казань

Authors

Kanazhevskiy Vladislav Vatslavovich ¹ , Chesalov Yuriy Aleksandrovich ¹ , Kochubey Dmitry Ivanovich ¹

Affiliations

1	Boreskov Institute of Catalysis SB RAS

Using EXAFS and vibrational spectroscopy a tightly bound solvation shell of H2PtCl6 in DMSO and water solutions is established. The shell contains H3O+, H5O2+ and DMSO molecules, depending on the solvent type. EXAFS suggests O-atoms of the shell are located at a distance of 3.7-4.4 Å from Pt. Complexes' structure was studied in wide concentration range DMSO and water solutions. The complexes are mononuclear and unhydrolyzed. Combining via the shell is possible

Kanazhevskiy V.V. , Chesalov Y.A. , Kochubey D.I.
Solvation Shell of Platinum Complexes in Solutions According to EXAFS Data
EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources” 30 Aug - 4 Sep 2015