Oxoiron(V) Intermediates that Oxygenate C=C and C-H Groups - Conference attendances | Sciact - CRIS-system of Boreskov Institute of Catalysis

Oxoiron(V) Intermediates that Oxygenate C=C and C-H Groups Conference attendances

Language

Английский

Participant type

Устный

Conference

EuropaCat-XIII: 13th European Congress on Catalysis
27-31 Aug 2017 , Florence

Authors

Zima A.M. ^1,2 , Lyakin O.Y. ^1,2 , Bryliakov K.P. ^1,2 , Talsi E.P. ^1,2

Affiliations

1	Boreskov Institute of Catalysis SB RAS
2	Novosibirsk National Research University

The active species of the catalyst systems based on biomimetic iron complexes with aminopyridine ligands and various oxidants were studied. Depending on the nature of aminopyridine ligand, the catalyst systems exhibit EPR signals of three types of iron-oxygen intermediates I – III that are able to directly oxygenate C=C and C–H groups at low temperatures. Catalyst systems based on considered iron complexes were compared towards enantioselective epoxidation of chalcone, chemoselective hydroxylation of cyclohexane and regioselective hydroxylation of adamantane

Zima A.M. , Lyakin O.Y. , Bryliakov K.P. , Talsi E.P.
Oxoiron(V) Intermediates that Oxygenate C=C and C-H Groups
EuropaCat-XIII: 13th European Congress on Catalysis 27-31 Aug 2017