CO PROX on Pt-M and Pt-MOx (M = Fe, Ni, Co) Model Catalysts: Catalytic Performance and Operando XRD Studies - Conference attendances | Sciact - CRIS-system of Boreskov Institute of Catalysis

CO PROX on Pt-M and Pt-MOx (M = Fe, Ni, Co) Model Catalysts: Catalytic Performance and Operando XRD Studies Conference attendances

Language

Английский

Participant type

Устный

Conference

EuropaCat-XIII: 13th European Congress on Catalysis
27-31 Aug 2017 , Florence

Authors

Potemkin D.I. ^1,2 , Filatov E.Yu. ^1,3 , Zadesenets A.V. ^1,3 , Snytnikov P.V. ^1,2 , Sobyanin V.A. ²

Affiliations

1	Novosibirsk National Research University
2	Boreskov Institute of Catalysis SB RAS
3	Nikolaev Institute of Inorganic Chemistry SB RAS

For the first time the phase-pure Pt0.5M0.5 (M = Fe, Co, Ni) solid solution and Pt-MOx metal-oxide composite model catalysts were synthesized via single-source precursors decomposition and evaluated in CO PROX. The remarkable synergetic effect of second metal (Fe, Ni, Co) addition was observed for both Pt0.5M0.5 and Pt-MOx systems. The synergism was associated with bifunctional nature of Pt0.5M0.5 and Pt-MOx catalysts and reaction occurrence at Pt-M interface. Pt-Co combination exhibited the highest activity in CO PROX. By the operando XRD technique the stability of Pt0.5Co0.5 unordered solid solution structure under CO PROX conditions was confirmed. While for Pt-Co3O4 metal-oxide composite Co3O4 reduction already at 50 °C was shown.

Potemkin D.I. , Filatov E.Y. , Zadesenets A.V. , Snytnikov P.V. , Sobyanin V.A.
CO PROX on Pt-M and Pt-MOx (M = Fe, Ni, Co) Model Catalysts: Catalytic Performance and Operando XRD Studies
EuropaCat-XIII: 13th European Congress on Catalysis 27-31 Aug 2017