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Synthesis of Ag-Modified Adsorptive-Catalytic Systems Based on ZSM-5 and γ-Al2O3 and Their Study under “Cold Start” Conditions Conference attendances

Language Английский
Participant type Устный
Conference 14th International Conference on Fundamental and Applied Aspects of Physical Chemistry
24-28 Sep 2018 , Belgrade
Authors Temerev Victor Leonidovich 1 , Vedyagin Aleksey Anatolʹevich 2 , Iost Kristina Nikolaevna 1 , Pirutko Larisa Vladimirovna 2 , Starokon Eugeny Vladimirovich 2 , Shubin Yury Viktorovich 3 , Plyusnin Pavel Evgenʹevich 3 , Cherepanova Svetlana Vitalievna 2 , Volodin Alexander Mikhailovich 2 , Kenzhin Roman Mugaramovich 2 , Stoyanovskii Vladimir Olegovich 2 , Shlyapin Dmitrii Andreevich 1
Affiliations
1 Institute of Hydrocarbons Processing SB RAS
2 Boreskov Institute of Catalysis SB RAS
3 Nikolaev Institute of Inorganic Chemistry SB RAS

Abstract: In the present work, adsorptive-catalytic properties of the system based on ZSM-5 zeolite and γ-Al2O3 as a binder were studied. Such system is considered to be used as adsorption trap within vehicle exhaust gas neutralization concept in order to solve so-called “cold start” problem. In aim to study modifying effect of silver on the properties of zeolite, such compositions as Ag/ZSM-5+γ-Al2O3 and HZSM-5+Ag/γ-Al2O3 were prepared. The silver loading was 10 wt.%. The samples were tested in a prompt thermal aging regime. The composition of the reaction mixture was varied to elucidate the effects of CO and hydrocarbons on the state of the active sites.
Cite: Temerev V.L. , Vedyagin A.A. , Iost K.N. , Pirutko L.V. , Starokon E.V. , Shubin Y.V. , Plyusnin P.E. , Cherepanova S.V. , Volodin A.M. , Kenzhin R.M. , Stoyanovskii V.O. , Shlyapin D.A.
Synthesis of Ag-Modified Adsorptive-Catalytic Systems Based on ZSM-5 and γ-Al2O3 and Their Study under “Cold Start” Conditions
14th International Conference on Fundamental and Applied Aspects of Physical Chemistry 24-28 Sep 2018