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Green Stereoselective Oxidations, Catalyzed by Bioinspired bis-Amine-bis-Pyridine Manganese Complexes Доклады на конференциях

Язык Английский
Тип доклада Устный
Url доклада https://www.accc7.org.my/images/Full_Programme_c.pdf
Конференция 7th Asian Conference on Coordination Chemistry
15-18 окт. 2019 , Kuala Lumpur
Авторы Оттенбахер Роман Викторович 1,2 , Брылякова Анна Александровна 2 , Талзи Евгений Павлович 1,2 , Брыляков Константин Петрович 1,2
Организации
1 Новосибирский национальный исследовательский государственный университет
2 Институт катализа им. Г.К. Борескова СО РАН

Реферат: In recent years, great efforts have been invested into the design of bioinspired manganese complexes, capable of conducting chemo- and stereoselective oxidations of complex organic molecules,1 such as asymmetric epoxidations, stereoselective and stereospecific C-H oxidations, oxidative desymmetrization of cyclic substrates, kinetic resolution of secondary alcohols, etc.2 In this contribution, we present an overview of the versatile catalytic reactivity of chiral bisamine-bis-pyridine manganese complexes, developed in our group and eslewhere, in a variety of asymmetric oxygenations with the environmentally benign oxidant hydrogen peroxide. Current understanding of the nature of the catalytically active, presumably high-valent manganese-oxo species, is presented.
Библиографическая ссылка: Ottenbacher R.V. , Bryliakova A.A. , Talsi E.P. , Bryliakov K.P.
Green Stereoselective Oxidations, Catalyzed by Bioinspired bis-Amine-bis-Pyridine Manganese Complexes
7th Asian Conference on Coordination Chemistry 15-18 Oct 2019