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Direct Reductive Amination of Aldehydes with Nitroarenes over Ag/Al2O3 Catalyst in a Continuous Flow Reactor Conference attendances

Language Английский
Participant type Стендовый
Conference EuropaCat-XIII: 13th European Congress on Catalysis
27-31 Aug 2017 , Florence
Authors Artiukha E.A. 1 , Nuzhdin A.L. 1 , Bukhtiyarova G.A. 1 , Bukhtiyarov V.I. 1
Affiliations
1 Boreskov Institute of Catalysis SB RAS

Abstract: For the first time, we report the results of direct reductive amination of aldehydes with nitroarenes over Ag/Al2O3 catalyst. Various secondary amines were obtained in yield up to 90% in a continuous flow reactor using molecular hydrogen as a reducing agent. Interestingly, the hydrogenation of reducible functional groups such as C=C, Cl and Br is almost absent in initial reactants and target products under the reaction conditions.
Cite: Artiukha E.A. , Nuzhdin A.L. , Bukhtiyarova G.A. , Bukhtiyarov V.I.
Direct Reductive Amination of Aldehydes with Nitroarenes over Ag/Al2O3 Catalyst in a Continuous Flow Reactor
EuropaCat-XIII: 13th European Congress on Catalysis 27-31 Aug 2017