Mixtures used in oxidizing alkyl aromatic compounds
Patents
| Language: |
Английский |
| Type: |
Invention |
| Number |
US 9045407 B2 |
| Request number: |
13/155,530 |
| Request date: |
Jun 8, 2011 |
| patent.field.start_date: |
|
| Registration date: |
Jun 2, 2015 |
| patent.field.request_publication_date: |
|
| Authors |
Bhattacharyya A.
,
Kocal J.A.
,
Walenga J.T.
,
Adonin N.Y.
,
Kuznetsova N.I.
,
Balʹzhinimaev B.S.
|
| Affiliations |
| 1 |
Boreskov Institute of Catalysis SB RAS
|
| 2 |
Honeywell UOP (formely UOP LLC)
|
|
A process and a mixture for oxidizing an alkyl-aromatic compound comprises forming a mixture comprising the alkyl-aromatic compound, a solvent, a bromine source, and a catalyst; and contacting the mixture with an oxidizing agent at oxidizing conditions to produce an oxidation product comprising at least one of an aromatic aldehyde, an aromatic alcohol, an aromatic ketone, and an aromatic carboxylic acid. The solvent comprises a carboxylic acid having from 1 to 7 carbon atoms and an ionic liquid selected from the group consisting of an imidazolium ionic liquid, a pyridinium ionic liquid, a phosphonium ionic liquid, a tetra alkyl ammonium ionic liquid, and combinations thereof. The catalyst comprises at least one of cobalt, titanium, manganese, chromium, copper, nickel, vanadium, iron, molybdenum, tin, cerium, and zirconium.