Process for preparing catalyst component for propylene polymerization
Patents
| Language: |
Английский |
| Type: |
Patent request |
| Number |
WO 2007134851 A1 |
| Request number: |
PCT/EP2007/004572 |
| Request date: |
May 23, 2007 |
| patent.field.start_date: |
|
| Registration date: |
|
| patent.field.request_publication_date: |
Nov 29, 2007 |
| Authors |
Ramjoie Y.
,
Vlaar M.
,
Friederichs N.H.
,
Sergeev S.A.
,
Zakharov V.A.
,
Bukatov G.D.
,
Taftaf M.
,
Aburaqabah A.
|
| Affiliations |
| 1 |
Saudi Basic Industries Corporation (Netherlands)
|
|
The invention relates to a process for preparing a polymerization catalyst component wherein a solid compound with formula Mg(OR1)xCl2-x wherein x is larger than O and smaller than 2, and each R1, independently, represents an alkyl group, said compound being obtained by reacting a Grignard compound with an alkoxy- or aryloxy-containing silane compound, is contacted with at least one activating compound selected from the group formed by internal electron donors and compounds of formula M(OR2)V-W(R3)W, wherein M can be Ti, Zr, Hf, Al or Si, each R2 and R3, independently, represent an alkyl, alkenyl or aryl group, v is the valency of M and w is smaller than v, in the presence of an inert dispersant to give an intermediate reaction product, and wherein the intermediate reaction product is contacted with a halogen-containing Ti-compound. A catalyst system comprising said component shows improved performance in olefin polymerization. The invention also relates to a polymerization catalyst system comprising the catalyst component and to a process of making a polyolefin by contacting at least one olefin with a polymerization catalyst system comprising the catalyst component.