Способ получения смеси ацетатов этиленгликоля
Patents
| Language: |
Русский |
| Type: |
Invention |
| Number |
SU 789506 A1 |
| Request number: |
2553838/23-04 |
| Request date: |
Dec 12, 1977 |
| patent.field.start_date: |
|
| Registration date: |
Dec 23, 1980 |
| patent.field.request_publication_date: |
|
| Authors |
Likholobov Vladimir Aleksandrovich
,
Volkhonskii M. G.
,
Ermakov Yurii I.
,
Mushenko D. V.
,
Lebedeva Éleonora Georgievna
,
Malov Yurii Ivanovich
,
Devekki Andrei Vasilʹevich
,
Barnakov Chingiz Nikolaevich
,
Yurʹev Yurii Nikolaevich
,
Chesnokov Boris Borisovich
,
Borisov Aleksei Vasilʹevich
,
Oshina Elena Leonidovna
|
| Affiliations |
| 1 |
Boreskov Institute of Catalysis SB RAS
|
|
The title acetates were prepd. by oxidn. of C2H4 with O in AcOH soln. at 50-90°/1-10 atm. The reaction was carried out in the presence of Pd chloride, an alkali metal chloride, and a N compd. (a nitrosyl complex of Fe, Ni, Ru, or Rh) in a 1:2-30:1-8 mol ratio. The nitrosyl complex was obtained by treating an appropriate metal chloride, sulfate, or carbonyl with nitric oxide or nitrosyl chloride.