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The catalyst and method of catalytic hydrogenation of hydroxycarboxylic acid esters to glycols Patents

Language: Английский
Type: Patent request
Number WO 2011036189 A1
Request number: PCT/EP2010/064001
Request date: Sep 22, 2010
patent.field.start_date:
Registration date:
patent.field.request_publication_date: Mar 31, 2011
Authors Demeshkina Margarita Petrovna , Khasin A.A. , Minjukova T.P. , Parmon Valentin Nikolaevich , Simakova Irina Leonidovna , Simonov Mikhail Nikolaevich , Jurieva T.M.
Affiliations
Abstract: The invention relates to processes for the low-cost production of glycols from esters of hydroxycarboxylic acids. The esters of hydroxycarboxylic acids and hydrogen in gas phase are contacted with the catalyst which contains hydroxysilicate of copper or reduced hydroxysilicate of copper. The reduced hydrosilicate of copper contains metallic copper nanoparticles decorated by amorphous oxyhydroxide of silicon. Such decorated copper nanoparticles have advantageous activity and selectivity in catalytic hydrogenation of hydroxycarboxylic acid esters to glycols.
Cite: Demeshkina M.P. , Khasin A.A. , Minjukova T.P. , Parmon V.N. , Simakova I.L. , Simonov M.N. , Jurieva T.M.
The catalyst and method of catalytic hydrogenation of hydroxycarboxylic acid esters to glycols
Number: WO2011036189A1, , Request number PCT/EP2010/064001 from Sep 22, 2010 ANCAN
Identifiers:
Chemical Abstracts: 2011:395870
Chemical Abstracts (print): 154:363392
Name: The catalyst and method of catalytic hydrogenation of hydroxycarboxylic acid esters to glycols
English name: The catalyst and method of catalytic hydrogenation of hydroxycarboxylic acid esters to glycols