Electrocatalytic Properties of Platinum Anchored to the Surface of Highly Oriented Pyrolytic Graphite Научная публикация
Журнал |
Russian Journal of Electrochemistry
ISSN: 1023-1935 , E-ISSN: 1608-3342 |
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Вых. Данные | Год: 2000, Том: 36, Номер: 9, Страницы: 952-959 Страниц : 8 DOI: 10.1007/BF02757507 | ||
Ключевые слова | Support Surface; Scanning Electron Micro; Highly Orient Pyrolytic Graphite; Potential Cycling; Electrocatalytic Property | ||
Авторы |
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Организации |
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Информация о финансировании (1)
1 | International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union | 95-0255 |
Реферат:
Nano-sized particles of platinum deposited on highly oriented pyrolytic graphite (HOPG) electrolessly (average sized = 3.4 nm) or electrochemically (d = 20 nm) and polycrystalline platinum are compared. The dispersed electrodes exhibit special features in the oxidation of ethylene glycol and adsorbed carbon monoxide. In particular, they reduce the overpotential of these processes. Possible reasons for the observed distinctions are discussed. The potential cycling leads to coalescence of nano-sized Pt particles on HOPG. As a result, their size distribution expands, and the distribution maximum shifts towards large sizes (d = 6.4 nm). This seriously complicates use of Pt/HOPG as a model electrode for investigating the size effect.
Библиографическая ссылка:
Savinova E.R.
, Lebedeva N.P.
, Simonov P.A.
, Kryukova G.N.
Electrocatalytic Properties of Platinum Anchored to the Surface of Highly Oriented Pyrolytic Graphite
Russian Journal of Electrochemistry. 2000. V.36. N9. P.952-959. DOI: 10.1007/BF02757507 WOS Scopus РИНЦ
Electrocatalytic Properties of Platinum Anchored to the Surface of Highly Oriented Pyrolytic Graphite
Russian Journal of Electrochemistry. 2000. V.36. N9. P.952-959. DOI: 10.1007/BF02757507 WOS Scopus РИНЦ
Оригинальная:
Савинова Е.Р.
, Лебедева Н.П.
, Симонов П.А.
, Крюкова Г.Н.
Электрокаталитические свойства платины, закрепленной на поверхности высокоориентированного пирографита
Электрохимия. 2000. Т.36. №9. С.1081-1088. РИНЦ РИНЦ
Электрокаталитические свойства платины, закрепленной на поверхности высокоориентированного пирографита
Электрохимия. 2000. Т.36. №9. С.1081-1088. РИНЦ РИНЦ
Даты:
Поступила в редакцию: | 1 июл. 1999 г. |
Опубликована в печати: | 1 сент. 2000 г. |
Идентификаторы БД:
Web of science | WOS:000089751000006 |
Scopus | 2-s2.0-0033780237 |
РИНЦ | 13338146 |
Chemical Abstracts | 2000:735636 |
Chemical Abstracts (print) | 134:34254 |
OpenAlex | W2026875455 |