Resonance Energy Transfer from Solid to Adsorbed Molecules under Radiolysis of the N2O-MgO System Научная публикация
Журнал |
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases 1972-1989 (Journal of the Chemical Society, Faraday Transactions 1990-1998, Physical Chemistry Chemical Physics 1999-present )
ISSN: 0300-9599 |
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Вых. Данные | Год: 1986, Том: 82, Номер: 3, Страницы: 815-829 Страниц : 15 DOI: 10.1039/F19868200815 | ||
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Организации |
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Реферат:
The radiolysis mechanism of nitrous oxide adsorbed on magnesia has been studied at 77 K using e.s.r. spectroscopy and chromatography. The radiative decomposition of nitrous oxide is shown to take place not only during the dissociative capture of electrons, but also during the interaction of its molecules with magnesia exitons. At a monolayer coverage θ < 0.75 the interaction of nitrous oxide with exitons of a solid involves both an ionic and a molecular mechanism, whereas at a monolayer coverage only a molecular mechanism is observed. In this case five magnesia exitons cause decomposition of seven nitrous oxide molecules. The transition from an ionic interaction between N2O molecules and exitons to a molecular one as a result of raising the irradiation temperature of nitrous oxide adsorbed on magnesia (θ= 0.5) has been revealed.
Библиографическая ссылка:
Volkov A.I.
Resonance Energy Transfer from Solid to Adsorbed Molecules under Radiolysis of the N2O-MgO System
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases 1972-1989 (Journal of the Chemical Society, Faraday Transactions 1990-1998, Physical Chemistry Chemical Physics 1999-present ). 1986. V.82. N3. P.815-829. DOI: 10.1039/F19868200815 WOS Scopus РИНЦ
Resonance Energy Transfer from Solid to Adsorbed Molecules under Radiolysis of the N2O-MgO System
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases 1972-1989 (Journal of the Chemical Society, Faraday Transactions 1990-1998, Physical Chemistry Chemical Physics 1999-present ). 1986. V.82. N3. P.815-829. DOI: 10.1039/F19868200815 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 15 апр. 1985 г. |
Идентификаторы БД:
Web of science | WOS:A1986A883800019 |
Scopus | 2-s2.0-0011908135 |
РИНЦ | 41732177 |
Chemical Abstracts | 1986:432804 |
Chemical Abstracts (print) | 105:32804 |
OpenAlex | W2037136062 |