Dynamic Model of Self-Oscillatory Evolution in Carbon Monoxide Oxidation over Pt(110) Научная публикация
Журнал |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Вых. Данные | Год: 1993, Том: 51, Номер: 1, Страницы: 211-217 Страниц : 7 DOI: 10.1007/BF02062498 | ||
Ключевые слова | Adsorption; Carbon monoxide; Catalysts; Mathematical models; Oscillations; Oxidation; Platinum; Reaction kinetics; Surface phenomena | ||
Авторы |
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Организации |
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Реферат:
Based on the proposed reaction mechanism of catalytic CO oxidation on a Pt(110) surface, which has been well supported by experimental data, a kinetic model (six ODE's) was constructed accounting for the dynamics of adsorbates on the surface. This model completely reproduces the qualitative features of the reaction dynamics under fixed parameters (T, PCO, PO2), i.e. induction period before the beginning of self-oscillations and further time evolution of shape, period and amplitude of self-oscillations up to the achievement of a stable limit cycle (or steady state). In addition, the model predicts the possibility of “bursting” regimes (intermittence) of self-oscillations.
Библиографическая ссылка:
Vishnevskii A.L.
, Elokhin V.I.
, Kutsovskaya M.L.
Dynamic Model of Self-Oscillatory Evolution in Carbon Monoxide Oxidation over Pt(110)
Reaction Kinetics and Catalysis Letters. 1993. V.51. N1. P.211-217. DOI: 10.1007/BF02062498 WOS Scopus РИНЦ
Dynamic Model of Self-Oscillatory Evolution in Carbon Monoxide Oxidation over Pt(110)
Reaction Kinetics and Catalysis Letters. 1993. V.51. N1. P.211-217. DOI: 10.1007/BF02062498 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 22 мар. 1993 г. |
Принята к публикации: | 3 мая 1993 г. |
Опубликована в печати: | 1 нояб. 1993 г. |
Идентификаторы БД:
Web of science | WOS:A1993MV59600028 |
Scopus | 2-s2.0-0027694006 |
РИНЦ | 31097924 |
Chemical Abstracts | 1994:201594 |
Chemical Abstracts (print) | 120:201594 |
OpenAlex | W2081688233 |