Some Aspects of Fundamental Chemistry of the Universal Extraction (UNEX) Process for the Simultaneous Separation of Major Radionuclides (Cesium, Strontium, Actinides, and Lanthanides) from Radioactive Wastes Научная публикация
Журнал |
Journal of Radioanalytical and Nuclear Chemistry
ISSN: 0236-5731 , E-ISSN: 1588-2780 |
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Вых. Данные | Год: 2006, Том: 267, Номер: 3, Страницы: 603-613 Страниц : 11 DOI: 10.1007/s10967-006-0114-9 | ||||||||
Ключевые слова | WATER-NITROBENZENE SYSTEM; POLYETHYLENE-GLYCOL; COBALT DICARBOLLIDE; NITRIC-ACID; SOLVENT; BARIUM | ||||||||
Авторы |
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Организации |
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Информация о финансировании (3)
1 | Civilian Research and Development Foundation | RC2-2342-ST-02 |
2 | United States Department of Energy | 81995 |
3 | United States Department of Energy | DE-AC07-05ID14517 |
Реферат:
Scientists at the Idaho National Laboratory (INL) and Khlopin Radium Institute (KRI) collaboratively developed and validated the concept of a Universal Extraction (UNEX) process for simultaneously removing the major radionuclides (Cs, Sr, actinides, and lanthanides) from acidic radioactive waste in a single solvent extraction process. The process chemistry is unique and complicated, since the extractants, chlorinated cobalt dicarbollide (CCD), polyethylene glycol (PEG), and diphenyl-N,N-di-n-butylcarbamoylmethylphosphine oxide (Ph2CMPO), operatesynergistically to extract the major radionuclides.A combination of classical chemistry techniques, infrared (IR) spectroscopy, and nuclear magnetic resonance (NMR) spectroscopy were utilized to identify and explain the structures formed in the organic phase with protons or metal ions. Model systems, CCD-PEG and CCD-bidentate organophosphorus compounds were studied and possible structures of complexes, existing in the organic phase, are proposed and properties of the UNEX extractant are discussed.
Библиографическая ссылка:
Luther T.A.
, Herbs R.S.
, Peterman D.R.
, Tillotson R.D.
, Garn T.G.
, Babain V.A.
, Smirnov I.V.
, Stoyanov E.S.
, Antonov N.G.
Some Aspects of Fundamental Chemistry of the Universal Extraction (UNEX) Process for the Simultaneous Separation of Major Radionuclides (Cesium, Strontium, Actinides, and Lanthanides) from Radioactive Wastes
Journal of Radioanalytical and Nuclear Chemistry. 2006. V.267. N3. P.603-613. DOI: 10.1007/s10967-006-0114-9 WOS Scopus РИНЦ
Some Aspects of Fundamental Chemistry of the Universal Extraction (UNEX) Process for the Simultaneous Separation of Major Radionuclides (Cesium, Strontium, Actinides, and Lanthanides) from Radioactive Wastes
Journal of Radioanalytical and Nuclear Chemistry. 2006. V.267. N3. P.603-613. DOI: 10.1007/s10967-006-0114-9 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 31 авг. 2005 г. |
Опубликована в печати: | 1 мар. 2006 г. |
Идентификаторы БД:
Web of science | WOS:000236555500014 |
Scopus | 2-s2.0-33344458275 |
РИНЦ | 13518587 |
Chemical Abstracts | 2006:169336 |
Chemical Abstracts (print) | 145:237057 |
OpenAlex | W2042242372 |