The Ageing of Silica Gels Affected by Hydrothermal Treatment Научная публикация
Журнал |
Zeitschrift fur Anorganische und Allgemeine Chemie
ISSN: 0044-2313 , E-ISSN: 1521-3749 |
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Вых. Данные | Год: 2011, Том: 637, Номер: 3-4, Страницы: 421-425 Страниц : 5 DOI: 10.1002/zaac.201000394 | ||||||||||
Ключевые слова | Energy storage, Hydrothermal syntheses, IR spectroscopy, Silicates, Solid state structure | ||||||||||
Авторы |
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Организации |
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Реферат:
Commercial silica gels of the pyrogenic and precipitated types were hydrothermally treated for 72 hours at temperatures between 90 °C and 210 °C in water of autogenous pressure. The samples were characterised by IR spectroscopy, water and nitrogen adsorption. Stability and sorption capacity run similarly. The more Q4 (Si(OSi)4) building units the framework of a silica gel contained, the lower was its sorption capacity. Sorption capacity increased with rising number of structural defects characterised by the presence of Q3 (Si(OSi)3OH) and Q2 (Si(OSi)2(OH)2) groups. Simultaneously, the hydrothermal stability of the silica material dropped off.
Библиографическая ссылка:
Lutz W.
, Weber M.
, Bertram R.
, Kurzhals R.
, Kryukova G.
The Ageing of Silica Gels Affected by Hydrothermal Treatment
Zeitschrift fur Anorganische und Allgemeine Chemie. 2011. V.637. N3-4. P.421-425. DOI: 10.1002/zaac.201000394 WOS Scopus РИНЦ
The Ageing of Silica Gels Affected by Hydrothermal Treatment
Zeitschrift fur Anorganische und Allgemeine Chemie. 2011. V.637. N3-4. P.421-425. DOI: 10.1002/zaac.201000394 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 29 окт. 2010 г. |
Принята к публикации: | 5 янв. 2011 г. |
Опубликована online: | 5 янв. 2011 г. |
Опубликована в печати: | 1 мар. 2011 г. |
Идентификаторы БД:
Web of science | WOS:000288516600015 |
Scopus | 2-s2.0-79952852093 |
РИНЦ | 16725486 |
Chemical Abstracts | 2011:349223 |
Chemical Abstracts (print) | 154:416893 |
OpenAlex | W2050749188 |