The Role of Subsurface Oxygen in Oscillatory Behaviour of CO+O2 Reaction over Pd Metal Catalysts: Monte Carlo Model Научная публикация
Конференция |
Physical Methods for Catalytic Research at the Molecular Level: International memorial K.I. Zamaraev conference 28 июн. - 2 июл. 1999 , Novosibirsk |
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Журнал |
Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169 |
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Вых. Данные | Год: 2000, Том: 158, Номер: 1, Страницы: 161-166 Страниц : 6 DOI: 10.1016/S1381-1169(00)00061-3 | ||||
Ключевые слова | Autowaves, CO oxidation, Monte Carlo model, Oscillations, Palladium | ||||
Авторы |
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Организации |
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Информация о финансировании (2)
1 | International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union | 1882 |
2 | Российский фонд фундаментальных исследований | 99-03-32433 |
Реферат:
The statistical lattice model constructed for (CO+O2)/Pd reaction takes into account the change of surface properties due to the penetration of the adsorbed oxygen into subsurface layer. The model demonstrates the oscillations of the rate of CO2 formation and the concentrations of the adsorbed species. Autowave processes on the model palladium surface accompany these oscillations. The existence of the reaction zone between the moving adsorbate islands characterised by the elevated concentration of the free active centres has been shown. The results obtained make it possible to interpret the surface processes on the atomic scale.
Библиографическая ссылка:
Latkin E.I.
, Elokhin V.I.
, Matveev A.V.
, Gorodetskii V.V.
The Role of Subsurface Oxygen in Oscillatory Behaviour of CO+O2 Reaction over Pd Metal Catalysts: Monte Carlo Model
Journal of Molecular Catalysis A: Chemical. 2000. V.158. N1. P.161-166. DOI: 10.1016/S1381-1169(00)00061-3 WOS Scopus РИНЦ
The Role of Subsurface Oxygen in Oscillatory Behaviour of CO+O2 Reaction over Pd Metal Catalysts: Monte Carlo Model
Journal of Molecular Catalysis A: Chemical. 2000. V.158. N1. P.161-166. DOI: 10.1016/S1381-1169(00)00061-3 WOS Scopus РИНЦ
Даты:
Опубликована online: | 18 июл. 2000 г. |
Опубликована в печати: | 8 сент. 2000 г. |
Идентификаторы БД:
Web of science | WOS:000089201200017 |
Scopus | 2-s2.0-0034622870 |
РИНЦ | 13360456 |
Chemical Abstracts | 2000:498678 |
Chemical Abstracts (print) | 133:199301 |
OpenAlex | W2001609191 |