A Kinetic Model of Standard Selective Catalytic Reduction of NO by NH3 on Single Sites Научная публикация
Журнал |
Reaction Kinetics, Mechanisms and Catalysis
ISSN: 1878-5190 , E-ISSN: 1878-5204 |
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Вых. Данные | Год: 2011, Том: 103, Номер: 1, Страницы: 11-18 Страниц : 8 DOI: 10.1007/s11144-011-0285-4 | ||||
Ключевые слова | Kinetics, NONH 3O 2 N 2H 2O, Reaction orders, Single catalytic sites, Surface chemical reactions | ||||
Авторы |
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Организации |
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Информация о финансировании (1)
1 | Chalmers University of Technology |
Реферат:
Reduction of NO by NH3 in the presence of O2 may occur on single Fe or Cu atoms or dimers incorporated into the inner walls of a zeolite. Although this process is of considerable intrinsic interest as an example of complex reactions running on single sites and is also important from the perspective of environmental chemistry, its mechanism is still open for debate. One of the likely schemes of the process implies the formation of N2 and H2O via the reaction of gas-phase NO and adsorbed NH3. The author presents a detailed analysis of the steady-state kinetics corresponding to this scheme. The model employed includes eleven elementary steps. The results obtained allow one to interpret the apparent reaction orders observed experimentally.
Библиографическая ссылка:
Zhdanov V.P.
A Kinetic Model of Standard Selective Catalytic Reduction of NO by NH3 on Single Sites
Reaction Kinetics, Mechanisms and Catalysis. 2011. V.103. N1. P.11-18. DOI: 10.1007/s11144-011-0285-4 WOS Scopus РИНЦ
A Kinetic Model of Standard Selective Catalytic Reduction of NO by NH3 on Single Sites
Reaction Kinetics, Mechanisms and Catalysis. 2011. V.103. N1. P.11-18. DOI: 10.1007/s11144-011-0285-4 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 24 сент. 2010 г. |
Принята к публикации: | 12 янв. 2011 г. |
Опубликована online: | 4 февр. 2011 г. |
Опубликована в печати: | 1 июн. 2011 г. |
Идентификаторы БД:
Web of science | WOS:000290169600002 |
Scopus | 2-s2.0-79960041370 |
РИНЦ | 18058156 |
Chemical Abstracts | 2011:545470 |
Chemical Abstracts (print) | 154:551516 |
OpenAlex | W2114786728 |