Interaction of Olefins with Carbon Monoxide on Zeolite H-ZSM-5. NMR Observation of the Friedel-Crafts Acylation of Alkenes at Ambient Temperature Full article
Journal |
Journal of the American Chemical Society
ISSN: 0002-7863 , E-ISSN: 1520-5126 |
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Output data | Year: 1996, Volume: 118, Number: 44, Pages: 10890-10891 Pages count : 2 DOI: 10.1021/ja9615381 | ||
Tags | STABLE CARBOCATIONS; CHEMISTRY; HZSM-5; IDENTIFICATION; HYDROCARBONS; CONVERSION; KETONES; ZSM-5; ETHER; ACID | ||
Authors |
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Affiliations |
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Funding (2)
1 | Russian Foundation for Basic Research | 95-03-08780 |
2 | International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union | 95-IN-RU-194 |
Abstract:
Under anhyd. conditions, olefins (ethene, isobutene, and 1-octene) react (within the zeolite) with CO on HZSM-5 at 296 K to give unsatd. ketones and stable 5-membered carboxonium ions. The first evidence was obtained for the Friedel-Crafts acylation of alkenes in zeolite catalysts at ambient temps. by acylium cations, generated in situ from CO and alkenes.
Cite:
Luzgin M.V.
, Romannikov V.N.
, Stepanov A.G.
, Zamaraev K.I.
Interaction of Olefins with Carbon Monoxide on Zeolite H-ZSM-5. NMR Observation of the Friedel-Crafts Acylation of Alkenes at Ambient Temperature
Journal of the American Chemical Society. 1996. V.118. N44. P.10890-10891. DOI: 10.1021/ja9615381 WOS Scopus РИНЦ
Interaction of Olefins with Carbon Monoxide on Zeolite H-ZSM-5. NMR Observation of the Friedel-Crafts Acylation of Alkenes at Ambient Temperature
Journal of the American Chemical Society. 1996. V.118. N44. P.10890-10891. DOI: 10.1021/ja9615381 WOS Scopus РИНЦ
Dates:
Submitted: | May 8, 1996 |
Published print: | Nov 6, 1996 |
Identifiers:
Web of science | WOS:A1996VR41900027 |
Scopus | 2-s2.0-0029840851 |
Elibrary | 13246886 |
Chemical Abstracts | 1996:625627 |
Chemical Abstracts (print) | 126:18472 |
OpenAlex | W2073750357 |